Synthesis of Renewable High-Density Fuel with Cyclopentanone Derived from Hemicellulose
文献类型：期刊论文
| 作者 | Li, Shanshan1; Li, Ning1,3; Li, Guangyi1,3; Wang, Wei1,2; Wang, Wentao1; Wang, Aiqin1,3; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1,3 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2017-02-01 |
| 卷号 | 5期号:2页码:1812-1817 |
| 关键词 | High Density Fuel Lignocellulose Cyclopentanone Aldol Condensation Selective Hydrogenation Hydrodeoxygenation |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.6b02554 |
| 文献子类 | Article |
| 英文摘要 | 1-(3-Cyclopentyl)cyclopenty1-2-cyclopentyl-cyclopentane, a renewable high-density fuel, was first produced in a high overall carbon yield (similar to 70%) with cyclopenanone that can be derived from hemicellulose. The synthetic route used in this work contains three steps. In the first step, 2-cyclopentyl cyclopentanone was synthesized for the first time by a one-pot reaction of cyclopentanone and hydrogen under the catalysis of Raney metal and alkali hydroxides. Over the optimized catalyst (Raney cobalt + KOH), a high carbon yield (83.3%) of 2-cyclopentyl-cyclopentanone was achieved at 353 K. In the second step, 2-cyclopentyl-5-(2-cyclopentylcyclopentylidene)-cyclopentanone was produced in a high carbon yield (95.4%) by the solvent-free self-aldol condensation of 2-cyclopentyl-cyclopentanone under the vacuum conditions. In the third step, the 2cyclopentyl-5-(2-cyclopentylcyclopentylidene)cyclopentanone was hydrodeoxygenated over the Ni-SiO2 catalyst under solvent free conditions. High carbon yields of 1-(3-cyclopentyl)cyclopentyl-2-cyclopentylcyclopentane (88.5%) and polycycloalkanes (99.0%) were obtained. The Ni-SiO2 catalyst was stable under investigated conditions. No evident deactivation was noticed during the 50 h time on stream. The as -obtained polycycloalkane mixture has a density of 0.943 g mL(-1) and a freezing point of 233.7 K. As a potential application, it can be blended into conventional high density fuels (e.g., JP-10) for rockets and missile propulsion. |
| WOS关键词 | LIQUID ALKANES ; LOW-TEMPERATURE ; AQUEOUS-PHASE ; WOODY BIOMASS ; DIMERIZATION ; CELLULOSE ; HYDRODEOXYGENATION ; LIGNOCELLULOSE ; TRANSFORMATION ; ISOMERIZATION |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000393634600065 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169646]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Ning; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Shaanxi Sci Tech Univ, Sch Chem & Environm Sci, Shaanxi Key Lab Catalysis, 1 Dongyihuan Rd, Hanzhong 723001, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat, iChEM, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shanshan,Li, Ning,Li, Guangyi,et al. Synthesis of Renewable High-Density Fuel with Cyclopentanone Derived from Hemicellulose[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(2):1812-1817. |
| APA | Li, Shanshan.,Li, Ning.,Li, Guangyi.,Wang, Wei.,Wang, Wentao.,...&Zhang, Tao.(2017).Synthesis of Renewable High-Density Fuel with Cyclopentanone Derived from Hemicellulose.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5(2),1812-1817. |
| MLA | Li, Shanshan,et al."Synthesis of Renewable High-Density Fuel with Cyclopentanone Derived from Hemicellulose".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5.2(2017):1812-1817. |
入库方式： OAI收割
来源：大连化学物理研究所
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