Total Syntheses of (-)-Hibiscone C and Lysergine: A Cyclization/Fragmentation Strategy
文献类型:期刊论文
| 作者 | Lu, Yandong1; Yuan, Haosen1; Zhou, Shijie2; Luo, Tuoping1,2 |
| 刊名 | ORGANIC LETTERS
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| 出版日期 | 2017-02-03 |
| 卷号 | 19期号:3页码:620-623 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.6b03778 |
| 文献子类 | Article |
| 英文摘要 | The first asymmetric total synthesis of (-)-hibiscone C and a concise synthesis of ergot alkaloid lysergine are described. Both syntheses were achieved using the radical cyclization/fragmentation strategy. This cascade reaction enabled the application of the strained bicycle as a synthon for the synthesis of highly substituted decalins in an efficient and stereoselective manner. |
| WOS关键词 | (+/-)-LYSERGIC ACID ; (+)-LYSERGIC ACID ; ERGOT ALKALOIDS ; HIBISCONE-C ; GMELOFURAN ; ROUTE ; PHOTOCYCLIZATION ; REDUCTION ; ENAMIDES ; DECALINS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000393539900049 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169658] ![]() |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Luo, Tuoping |
| 作者单位 | 1.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Acad Adv Interdisciplinary Studies, Peking Tsinghua Ctr Life Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Yandong,Yuan, Haosen,Zhou, Shijie,et al. Total Syntheses of (-)-Hibiscone C and Lysergine: A Cyclization/Fragmentation Strategy[J]. ORGANIC LETTERS,2017,19(3):620-623. |
| APA | Lu, Yandong,Yuan, Haosen,Zhou, Shijie,&Luo, Tuoping.(2017).Total Syntheses of (-)-Hibiscone C and Lysergine: A Cyclization/Fragmentation Strategy.ORGANIC LETTERS,19(3),620-623. |
| MLA | Lu, Yandong,et al."Total Syntheses of (-)-Hibiscone C and Lysergine: A Cyclization/Fragmentation Strategy".ORGANIC LETTERS 19.3(2017):620-623. |
入库方式: OAI收割
来源:大连化学物理研究所
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