Phenyltrichlorosilane-functionalized magnesium oxide microspheres: Preparation, characterization and application for the selective extraction of dioxin-like polycyclic aromatic hydrocarbons in soils with matrix solid-phase dispersion
文献类型：期刊论文
| 作者 | Tan, Dongqin1,2; Jin, Jing1; Li, Fang3; Sun, Xiaoli4; Dhanjai1; Ni, Yuwen1; Chen, Jiping1 |
| 刊名 | ANALYTICA CHIMICA ACTA
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 956页码:14-23 |
| ISSN号 | 0003-2670 |
| 关键词 | Matrix Solid-phase Dispersion Phenyltrichlorosilane Magnesium Oxide Dioxin-like Polycyclic Aromatic Hydrocarbons |
| DOI | 10.1016/j.aca.2016.12.040 |
| 文献子类 | Article |
| 英文摘要 | Magnesium oxide microspheres functionalized with phenyltrichlorosilane (PTS-MgO) were synthesized by surface modification through silanization reaction, which was confirmed by Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetry analysis (TGA) and N-2 adsorption-desorption. The result indicated that PTS-MgO not only possessed the ability of enhancing the retention with PAHs, but also weakening the interference from chlorinated compounds. As a sorbent for the matrix solid-phase dispersion (MSPD) extraction, PTS-MgO was used to selectively extract seven dioxin-like polycyclic aromatic hydrocarbons (DL-PAHs) from soil samples. Various parameters affecting the recoveries of seven DL-PAHs were investigated and optimized, such as sorbent/sample mass ratio, grinding time, rinsing and eluting conditions. Under the optimized conditions, the developed method combining MSPD with HPLC-FLD exhibited good sensitivity (0.02-0.12 ng g(-1) detection of limits) and linearity (linear correlation coefficient greater than 0.9997). Satisfactory recoveries with DL-PAHs spiked at two levels (10 and 80 ng g-1) were obtained in the range of 72.2-113.1% with RSD < 9.6%, indicating that PTS-MgO had a potential in MSPD extraction of DL-PAHs in soils. Additionally, the proposed MSPD-HPLC-FLD method was also verified by detecting seven DL-PAHs in the standard reference soil. Based on the developed method, DL-PAHs in soil samples were detected with the concentration ranging from 70.08 to 555.05 ng g(-1) dry weight (dw). The total toxic equivalency quotients (TEQ) of seven DL-PAHs varied from 9.93 to 143.94 ng TEQ/g dw. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | PERFORMANCE LIQUID-CHROMATOGRAPHY ; MICROWAVE-ASSISTED EXTRACTION ; RETENTION BEHAVIOR ; SOXHLET EXTRACTION ; URBAN SOILS ; SAMPLES ; PAHS ; MICROEXTRACTION ; CONTAMINATION ; PERSPECTIVE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000393252000002 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169668]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Chen, Jiping |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China 4.Lishui Univ, Dept Chem, Lishui 32300, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Dongqin,Jin, Jing,Li, Fang,et al. Phenyltrichlorosilane-functionalized magnesium oxide microspheres: Preparation, characterization and application for the selective extraction of dioxin-like polycyclic aromatic hydrocarbons in soils with matrix solid-phase dispersion[J]. ANALYTICA CHIMICA ACTA,2017,956:14-23. |
| APA | Tan, Dongqin.,Jin, Jing.,Li, Fang.,Sun, Xiaoli.,Dhanjai.,...&Chen, Jiping.(2017).Phenyltrichlorosilane-functionalized magnesium oxide microspheres: Preparation, characterization and application for the selective extraction of dioxin-like polycyclic aromatic hydrocarbons in soils with matrix solid-phase dispersion.ANALYTICA CHIMICA ACTA,956,14-23. |
| MLA | Tan, Dongqin,et al."Phenyltrichlorosilane-functionalized magnesium oxide microspheres: Preparation, characterization and application for the selective extraction of dioxin-like polycyclic aromatic hydrocarbons in soils with matrix solid-phase dispersion".ANALYTICA CHIMICA ACTA 956(2017):14-23. |
入库方式： OAI收割
来源：大连化学物理研究所
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