Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3)(3)
文献类型：期刊论文
| 作者 | Tan, Yuan2; Lang, Rui2; Li, Tianbo2,3; Matsumura, Daiju4; Miao, Shu2; Ren, Yujing2; Cui, Yi-Tao1; Qiao, Botao2; Li, Lin2; Wang, Aiqin2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 55期号:52页码:16054-16058 |
| 关键词 | Heterogeneous Catalysis Hydroformylation Rhodium Single-atom Catalysts Styrene |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201607885 |
| 文献子类 | Article |
| 英文摘要 | Homogeneous catalysts generally possess superior catalytic performance compared to heterogeneous catalysts. However, the issue of catalyst separation and recycling severely limits their use in practical applications. Single-atom catalysts have the advantages of both homogeneous catalysts, such as isolated sites, and heterogeneous catalysts, such as stability and reusability, and thus would be a promising alternative to traditional homogeneous catalysts. In the hydroformylation of olefins, single-atom Rh catalysts supported on ZnO nanowires demonstrate similar efficiency (TON approximate to 40000) compared to that of homogeneous Wilkinson's catalyst (TON approximate to 19000). HAADF-STEM and infrared CO chemisorption experiments identified isolated Rh atoms on the support. XPS and XANES spectra indicate that the electronic state of Rh is almost metallic. The catalysts are about one or two orders of magnitude more active than most reported heterogeneous catalysts and can be reused four times without an obvious decline in activity. |
| WOS关键词 | CERIA CATALYSTS ; CHEMISORBED CO ; REDUCTION ; OXIDATION ; RH ; HYDROGENATION ; PALLADIUM ; FRAMEWORK ; NANORODS ; SITES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000392875700015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169690]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Qiao, Botao; Zhang, Tao |
| 作者单位 | 1.Univ Tokyo, Synchrotron Radiat Res Org, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Japan Atom Energy Agcy, SPring 8,1-1-1 Kouto, Sayo, Hyogo 6795148, Japan |
| 推荐引用方式 GB/T 7714 | Tan, Yuan,Lang, Rui,Li, Tianbo,et al. Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3)(3)[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(52):16054-16058. |
| APA | Tan, Yuan.,Lang, Rui.,Li, Tianbo.,Matsumura, Daiju.,Miao, Shu.,...&Zhang, Tao.(2016).Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3)(3).ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(52),16054-16058. |
| MLA | Tan, Yuan,et al."Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3)(3)".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.52(2016):16054-16058. |
入库方式： OAI收割
来源：大连化学物理研究所
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