Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers
文献类型：期刊论文
| 作者 | Zhao, Zong-bao2; Chen, Qin1; Du, Jie-hao1; Xie, Hai-bo1; Zheng, Qiang1 |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2016-10-20 |
| 期号 | 10页码:1330-1358 |
| 关键词 | Catalytic Biorefinery Bio-based Monomers Bio-based Polymers Thermal Properties Mechanical Properties |
| ISSN号 | 1000-3304 |
| DOI | 10.11777/j.issn1000-3304.2016.16154 |
| 文献子类 | Review |
| 英文摘要 | The search for sustainable resource for polymers production have been obtained much attentions due to the over exploration of fossil resources and environment problems arisen from the use of petroleum based polymeric materials. The modern biorefinery produced a spectrum of biobased chemicals, which can be further upgraded into polymeric monomers for polymer synthesis. This review summarized the latest progress in the synthesis of biobased polymeric monomers from renewable resources such as carbohydrates, lignocellulose and plan oils. According to their structure, those biobased polymeric monomers can be categorised into aliphatic monomers and aromatic monomers including acids, diols, furyl and vanillic monomers. Various strategies, such as catalytic process and fementaion process, were compared in terms of selectivity, yield and feasibility of target biobased monomers. Those biobased monomers can be directly employed as feedstock to prepare biobased polymers, such as polyesters, polyamides, polycarbonates, polyurethanes and polyethers. Besides, both the traditional and novel polymerization processes can be adopted to prepare biobased polymers, such as catalyst free melt condensation, radical polymerization, photocuring process, proton transfer polymerization and enzymatic polycondensations. The influence of various heating methods, catalyst loading, mole ratio, reaction time and temperature to prepare biobased polymers were compared. Those biobased polymers exhibit excellent mechanical and thermal properties and promising properties such as shape memory effect, self-healing properties and bacteria clearing effect, which revealed great potential to replace the petroleum based polymers. Finally, the future development of bio-based polymers has also discussed. |
| WOS关键词 | RENEWABLE RESOURCES ; AEROBIC OXIDATION ; FERULIC ACID ; GAMMA-BUTYROLACTONE ; ITACONIC ACID ; POLY(FERULIC ACID-CO-TYROSINE) ; THERMOSETTING RESINS ; EPSILON-CAPROLACTONE ; POLYESTERS SYNTHESIS ; DELTA-VALEROLACTONE |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000387628200005 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169716]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xie, Hai-bo |
| 作者单位 | 1.Guizhou Univ, Coll Mat & Met, Dept Polymer Mat & Engn, Guiyang 550025, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Zong-bao,Chen, Qin,Du, Jie-hao,et al. Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers[J]. ACTA POLYMERICA SINICA,2016(10):1330-1358. |
| APA | Zhao, Zong-bao,Chen, Qin,Du, Jie-hao,Xie, Hai-bo,&Zheng, Qiang.(2016).Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers.ACTA POLYMERICA SINICA(10),1330-1358. |
| MLA | Zhao, Zong-bao,et al."Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers".ACTA POLYMERICA SINICA .10(2016):1330-1358. |
入库方式： OAI收割
来源：大连化学物理研究所
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