Nonresonant Vibrational Energy Transfer on Metal Nanoparticle/Liquid Interface
文献类型：期刊论文
| 作者 | Zheng, Junrong1,3; Li, Jiebo1,3; Yuan, Kaijun2; Chen, Hailong1; Miranda, Andrea1; Shen, Yuneng2; Jiang, Bo1,2; Chen, Yajing2; Zhang, Yufan1; Guo, Xunmin1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2016-11-10 |
| 卷号 | 120期号:44页码:25173-25179 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/acs.jpcc.6b03777 |
| 文献子类 | Article |
| 英文摘要 | Knowledge of vibrational energy transfer on a metal nanoparticle/liquid interface is essential for understanding the energy conversion process involved in many heterogeneous nanocatalyses. In this study, we investigate mode-specific vibrational energy transfer between CO molecules on different adsorbate sites on a 1 nm platinum metal nanoparticle/liquid interface by using ultrafast two-dimensional IR spectroscopy. The vibrational energy transport is found to be induced by vibration/vibration coupling with very little surface electron/vibration mediation. The energy transfer rate is determined to be about 1/140 ps(-1) from the atop site CO to the bridge site CO, and the specific rate is around 1/400 ps(-1) between the two nearest adsorbates. The energy transfer between different adsorbate sites can be described by the dephasing mechanism reasonably well. The mechanical coupling may contribute to the transfer, but analyses suggest that the role of dipole/dipole interaction is a more important factor for the energy transfer. |
| WOS关键词 | 2D IR SPECTROSCOPY ; AQUEOUS-SOLUTIONS ; INFRARED-SPECTROSCOPY ; CHEMICAL-DYNAMICS ; ECHO SPECTROSCOPY ; CO ADSORPTION ; SURFACES ; MOLECULES ; LIQUIDS ; TIME |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000387737900002 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169722]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zheng, Junrong |
| 作者单位 | 1.Rice Univ, Dept Chem, POB 1892, Houston, TX 77005 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China 3.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Junrong,Li, Jiebo,Yuan, Kaijun,et al. Nonresonant Vibrational Energy Transfer on Metal Nanoparticle/Liquid Interface[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(44):25173-25179. |
| APA | Zheng, Junrong.,Li, Jiebo.,Yuan, Kaijun.,Chen, Hailong.,Miranda, Andrea.,...&Guo, Xunmin.(2016).Nonresonant Vibrational Energy Transfer on Metal Nanoparticle/Liquid Interface.JOURNAL OF PHYSICAL CHEMISTRY C,120(44),25173-25179. |
| MLA | Zheng, Junrong,et al."Nonresonant Vibrational Energy Transfer on Metal Nanoparticle/Liquid Interface".JOURNAL OF PHYSICAL CHEMISTRY C 120.44(2016):25173-25179. |
入库方式： OAI收割
来源：大连化学物理研究所
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