Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes
文献类型：期刊论文
| 作者 | Zhang, Zhikun2; Chu, Wen-Dao2; Zhang, Lei2; Zhou, Qi2; Mo, Fanyang2; Zhang, Yan2; Wang, Jianbo1,2 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2016-11-09 |
| 卷号 | 138期号:44页码:14558-14561 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.6b09674 |
| 文献子类 | Article |
| 英文摘要 | A highly enantioselective synthesis of trisubstituted allenes has been achieved through Cu(I)-catalyzed cross-coupling of aryldiazoalkanes and terminal alkynes with chiral bisoxazoline ligands. Alkynyl migratory insertion of Cu(I) carbene is proposed as the key step for the construction of axial chirality. |
| WOS关键词 | CATALYTIC ASYMMETRIC-SYNTHESIS ; AXIALLY CHIRAL ALLENES ; N-TOSYLHYDRAZONES ; PROPARGYLIC PHOSPHATES ; ALPHA-DIAZOESTERS ; EFFICIENT SYNTHESIS ; KINETIC RESOLUTION ; DIAZO-COMPOUNDS ; ALDOL REACTION ; ALLENOATES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000387625300010 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169726]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci BNLMS,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhikun,Chu, Wen-Dao,Zhang, Lei,et al. Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016,138(44):14558-14561. |
| APA | Zhang, Zhikun.,Chu, Wen-Dao.,Zhang, Lei.,Zhou, Qi.,Mo, Fanyang.,...&Wang, Jianbo.(2016).Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,138(44),14558-14561. |
| MLA | Zhang, Zhikun,et al."Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138.44(2016):14558-14561. |
入库方式： OAI收割
来源：大连化学物理研究所
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