A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties
文献类型：期刊论文
| 作者 | Jiang, Heqing2; Jiao, Chengli2; Jiang, Xia1; Chu, Hailiang3; Sun, Lixian3 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:44页码:8683-8687 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/c6ce01827k |
| 文献子类 | Article |
| 英文摘要 | A novel 3D mixed-valent Cu-I/Cu-II metal-organic framework has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, photoluminescence spectroscopy, thermal gravimetric analysis, and powder X-ray diffraction. The structure possesses a 3D open framework constructed from the linkages of 1D [Cu-I(4,4'-bipy)](n) chains with [Cu-II(oda)(2)](2-) cationic subunits. The chemical sensing properties of this MOF have been studied by the quartz crystal microbalance technique. The framework exhibits good selectivity and sensitivity to water with respect to other organic solvents in view of chemical sensing applications. |
| WOS关键词 | COORDINATION POLYMER ; SOLVENT MOLECULES ; LIGAND ; LUMINESCENCE ; COMPLEXES ; CATALYSTS ; SORPTION ; SENSORS ; BINDING ; METHANE |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000387975900018 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169730]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Jiang, Heqing; Sun, Lixian |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Heqing,Jiao, Chengli,Jiang, Xia,et al. A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties[J]. CRYSTENGCOMM,2016,18(44):8683-8687. |
| APA | Jiang, Heqing,Jiao, Chengli,Jiang, Xia,Chu, Hailiang,&Sun, Lixian.(2016).A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties.CRYSTENGCOMM,18(44),8683-8687. |
| MLA | Jiang, Heqing,et al."A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties".CRYSTENGCOMM 18.44(2016):8683-8687. |
入库方式： OAI收割
来源：大连化学物理研究所
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