Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis
文献类型：期刊论文
| 作者 | Li, Yingzi2; Yu, Songjie1; Kong, Lingheng1; Zhou, Xukai1; Tang, Guodong1; Lan, Yu2; Li, Xingwei1 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2016-11-01 |
| 卷号 | 6期号:11页码:7744-7748 |
| 关键词 | Acylation C-h Activation Rhodium Ketene Arene |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.6b02668 |
| 文献子类 | Article |
| 英文摘要 | Carbonyl groups are ubiquitous in functional molecules. Although C-H bond acylation has been well studied via different mechanisms, transition-metal-catalyzed redox-neutral C(sp(3))-H acylation under mild conditions is unprecedented. In this work, ketene is designed as a acylating reagent for both C(sp(3))-H and C(sp(2))-H bonds under Rh(III) catalysis, affording a diverse array of carbonyl compounds in high yields and high atom economy under mild conditions. |
| WOS关键词 | C-H BOND ; ALPHA-OXOCARBOXYLIC ACIDS ; OXIDATIVE ORTHO-ACYLATION ; O-METHYL OXIMES ; DECARBOXYLATIVE ACYLATION ; PHOTOREDOX CATALYSIS ; TOLUENE DERIVATIVES ; DUAL ACTIVATION ; DIRECTING GROUP ; ALDEHYDES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000387306100053 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169734]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lan, Yu; Li, Xingwei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chongqing Univ, Sch Chem & Chem Engn, Chongqing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yingzi,Yu, Songjie,Kong, Lingheng,et al. Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis[J]. ACS CATALYSIS,2016,6(11):7744-7748. |
| APA | Li, Yingzi.,Yu, Songjie.,Kong, Lingheng.,Zhou, Xukai.,Tang, Guodong.,...&Li, Xingwei.(2016).Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis.ACS CATALYSIS,6(11),7744-7748. |
| MLA | Li, Yingzi,et al."Mild Acylation of C(sp(3))-H and C(sp(2))-H Bonds under Redox-Neutral Rh(III) Catalysis".ACS CATALYSIS 6.11(2016):7744-7748. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。