Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60
文献类型：期刊论文
| 作者 | Lou, Ning2; Xu, Dan2; Gan, Liangbing1,2; Li, Yanbang2; Zhang, Gaihong2,3; Wang, Dian2; Xu, Beidi2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-11-14 |
| 卷号 | 55期号:47页码:14590-14594 |
| 关键词 | Copper Complex Fullerenes Guanidine Heterocycles Macrocycle |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201606856 |
| 文献子类 | Article |
| 英文摘要 | A 14-membered heterocycle is created on the C-60 cage skeleton through a multistep procedure. Key steps involve repeated PCl5-induced hydroxylamino N-O bond cleavage leading to insertion of nitrogen atoms, and also piperidine-induced peroxo O-O bond cleavage leading to insertion of oxygen atoms. The hetero atoms form one pyrrole, two pyran, and one diazepine rings in conjunction with the C-60 skeleton carbon atoms. The fullerene-based macrocycle showed unique reactivities towards fluoride ion and copper salts. |
| WOS关键词 | OPEN-CAGE FULLERENES ; ARYLBORONIC ACIDS ; HETEROFULLERENES ; ENCAPSULATION ; ORIFICES ; PEROXIDE ; MOLECULE ; ANILINES ; HYDROGEN ; C58N2 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000388252700014 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169746]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Zhengzhou Univ Light Ind, Sch Food & Bioengn, Zhengzhou 450002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lou, Ning,Xu, Dan,Gan, Liangbing,et al. Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(47):14590-14594. |
| APA | Lou, Ning.,Xu, Dan.,Gan, Liangbing.,Li, Yanbang.,Zhang, Gaihong.,...&Xu, Beidi.(2016).Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(47),14590-14594. |
| MLA | Lou, Ning,et al."Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C-60".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.47(2016):14590-14594. |
入库方式： OAI收割
来源：大连化学物理研究所
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