Highly dispersed Pd/AlPO-5 catalyst for catalytic hydrogenation of 2-ethylanthraquinone
文献类型：期刊论文
| 作者 | Chen, Haijun2,3; Wang, Shudong2,3; Li, Xiaotong1,2,3; Su, Hongjiu2,3; Li, Dawei1,2,3; Yang, Xiaoye2,3 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2016-11-25 |
| 卷号 | 528页码:168-174 |
| 关键词 | Pd Catalyst Metal-support Interaction Anthraquinone Dispersion |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2016.10.007 |
| 文献子类 | Article |
| 英文摘要 | Highly dispersed Pd/AlPO-5 catalyst was prepared and tested in the hydrogenation of 2-ethylanthraquinone. Characterization results suggested that the abundant surface P-OH groups of AlPO-5 zeolite substituted NH3 ligands of [Pd(NH3)(4)](2+) precursor to form [Pd(NH3)(3)(POH)](2+). After calcination, the latter formed Pd-O-P interfacial linkage between Pd nanoparticles and AlPO-5, benefiting the suppression of Pd sintering. SiO2 and SiO2-AlPO-5 composite were used as supports for comparison. Catalyst supported on SiO2-AlPO-5 composite (25 wt% AlPO-5) exhibited improved catalytic activity and stability in consideration of reactant activation as well as the mass transfer of reactant molecules, which is expected to decrease precious metal loading in industrial application. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | METAL-SUPPORT INTERACTIONS ; ANTHRAQUINONE PROCESS ; PALLADIUM CATALYSTS ; PEROXIDE PRODUCTION ; NANOPARTICLES ; PLATINUM ; NAY ; REDISPERSION ; MECHANISM ; ALUMINA |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000388153300019 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169772]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Shudong; Su, Hongjiu |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 3.Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Haijun,Wang, Shudong,Li, Xiaotong,et al. Highly dispersed Pd/AlPO-5 catalyst for catalytic hydrogenation of 2-ethylanthraquinone[J]. APPLIED CATALYSIS A-GENERAL,2016,528:168-174. |
| APA | Chen, Haijun,Wang, Shudong,Li, Xiaotong,Su, Hongjiu,Li, Dawei,&Yang, Xiaoye.(2016).Highly dispersed Pd/AlPO-5 catalyst for catalytic hydrogenation of 2-ethylanthraquinone.APPLIED CATALYSIS A-GENERAL,528,168-174. |
| MLA | Chen, Haijun,et al."Highly dispersed Pd/AlPO-5 catalyst for catalytic hydrogenation of 2-ethylanthraquinone".APPLIED CATALYSIS A-GENERAL 528(2016):168-174. |
入库方式： OAI收割
来源：大连化学物理研究所
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