Synthesis of High-Density Aviation Fuel with Cyclopentanol
文献类型：期刊论文
| 作者 | Wang, Xiaodong2; Hu, Yancheng2; Wang, Wentao2; Wang, Aiqin1,2; Chen, Fang2,3; Li, Ning1,2; Cong, Yu2; Yang, Xiaofeng2; Zhang, Tao1,2; Li, Lin2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2016-11-01 |
| 卷号 | 4期号:11页码:6160-6166 |
| 关键词 | Jet Fuel Lignocellulose Cyclopentanol Dehydration Oligomerization/rearrangement Solid Acid Catalyst |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.6b01678 |
| 文献子类 | Article |
| 英文摘要 | Decalin is the main component of JP-900, a thermally stable and high-energy density jet fuel. Decalin is also an important component of advanced jet fuels. Cyclopentanol is a platform compound that can be derived from lignocellulose. In this work, a mixture of C-10 and C-15 polycycloalkanes (with decalin as the major component) was first synthesized by the oligomerization/rearrangement of cyclopentene from the dehydration of cyclopentanol, followed by hydrogenation. Among the investigated catalysts, Amberlyst-36 resin demonstrated the highest activity and excellent stability for cyclopentanol dehydration and cyclopentene oligomerization/rearrangement. The influences of reaction temperature and reaction time on the catalytic performances of Amberlyst-36 resin for both reactions were investigated. Under the optimum conditions, 84.0% carbon yield of cyclopentene was obtained from cyclopentanol dehydration, and 74.2% carbon yield of C-10 and C-15 polycycloalkenes was achieved by the oligomerization/rearrangement of cyclopentene. Finally, the C-10 and C-15 polycycloalkenes from the oligomerization/rearrangement of cyclopentene were further hydrogenated to a mixture of C-10 and C-15 polycycloalkanes with decalin as the major component (77% selectivity). This polycycloalkane mixture has high density (0.896 g mL(-1)). As a potential application, it can be used as an additive to improve the volumetric calorific values of conventional biojet fuels. |
| WOS关键词 | AROMATIC-HYDROCARBONS ; TRANSPORTATION FUELS ; CATALYTIC CONVERSION ; GAMMA-VALEROLACTONE ; PLATFORM MOLECULES ; LIQUID ALKANES ; JET-FUEL ; BIOMASS ; ACID ; LIGNOCELLULOSE |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000387428700042 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169790]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Ning; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat iChEM, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiaodong,Hu, Yancheng,Wang, Wentao,et al. Synthesis of High-Density Aviation Fuel with Cyclopentanol[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(11):6160-6166. |
| APA | Wang, Xiaodong.,Hu, Yancheng.,Wang, Wentao.,Wang, Aiqin.,Chen, Fang.,...&Li, Shanshan.(2016).Synthesis of High-Density Aviation Fuel with Cyclopentanol.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(11),6160-6166. |
| MLA | Wang, Xiaodong,et al."Synthesis of High-Density Aviation Fuel with Cyclopentanol".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.11(2016):6160-6166. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。