A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond
文献类型：期刊论文
| 作者 | Wu, Zhongshuai2; Xing, Tianzhu1; Du, Yan1; Ma, Lin1; Zhang, Xiangdong1; Ge, Chunhua1; Ji, Xiaochun1; Xue, Lili1; Wang, Rui1 |
| 刊名 | JOURNAL OF POROUS MATERIALS
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 23期号:6页码:1537-1545 |
| 关键词 | Carbon Spheres Mofs Composites Catalysis |
| ISSN号 | 1380-2224 |
| DOI | 10.1007/s10934-016-0214-z |
| 文献子类 | Article |
| 英文摘要 | A new composite (CCSs/MOFs) of carboxyl-rich carbon spheres (CCSs) and copper-based metal-organic frameworks (MOFs) was for the first time prepared. The CCSs/MOFs composite was synthesized by the coordinated growth of high surface area and porous MOFs, [Cu-3(BTC)(2)(H2O)](n) (HKUST-1), on the surface of the functionalized CCSs obtained through a one-step hydrothermal carbonization of glucose with acrylic acid at 180 A degrees C for 24 h. The resulting composites showed a core/shell structure with a tunable diameter arranging from 0.6 to 3.0 mu m, and possessed high specific surface area of 495 m(2)/g and nanoporous structures derived from MOFs. Further, the catalytic oxidation of benzylic alcohol to benzaldehyde as its application was studied. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; OXIDE COMPOSITES ; CORE-SHELL ; BENZYL ALCOHOL ; ADSORPTION ; OXIDATION ; MICROSPHERES ; CATALYST ; AMMONIA ; STORAGE |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000387111500014 |
| 出版者 | SPRINGER |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169818]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Xiangdong |
| 作者单位 | 1.Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Zhongshuai,Xing, Tianzhu,Du, Yan,et al. A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond[J]. JOURNAL OF POROUS MATERIALS,2016,23(6):1537-1545. |
| APA | Wu, Zhongshuai.,Xing, Tianzhu.,Du, Yan.,Ma, Lin.,Zhang, Xiangdong.,...&Wang, Rui.(2016).A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond.JOURNAL OF POROUS MATERIALS,23(6),1537-1545. |
| MLA | Wu, Zhongshuai,et al."A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond".JOURNAL OF POROUS MATERIALS 23.6(2016):1537-1545. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。