中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of a highly efficient 3D graphene-CNT-MnO2-PANI nanocomposite as a binder free electrode material for supercapacitors

文献类型:期刊论文

作者Rashad, Muhammad3; Asif, Muhammad1,2; Tan, Yi1; Pan, Lujun2; Li, Jiayan1; Fu, Xin2; Cui, Ruixue2
刊名PHYSICAL CHEMISTRY CHEMICAL PHYSICS
出版日期2016-10-14
卷号18期号:38页码:26854-26864
ISSN号1463-9076
DOI10.1039/c6cp04996f
文献子类Article
英文摘要Graphene based nanocomposites have been investigated intensively, as electrode materials for energy storage applications. In the current work, a graphene-CNT-MnO2-PANI (GCM@PANI) nanocomposite has been synthesized on 3D graphene grown on nickel foam, as a highly efficient binder free electrode material for supercapacitors. Interestingly, the specific capacitance of the synthesized electrode increases up to the first 1500 charge-discharge cycles, and is thus referred to as an electrode activation process. The activated GCM@PANI nanocomposite electrode exhibits an extraordinary galvanostatic specific capacitance of 3037 F g(-1) at a current density of 8 A g(-1). The synthesized nanocomposite exhibits an excellent cyclic stability with a capacitance retention of 83% over 12000 charge-discharge cycles, and a high rate capability by retaining a specific capacitance of 84.6% at a current density of 20 A g(-1). The structural and electrochemical analysis of the synthesized nanocomposite suggests that the astonishing electrochemical performance might be attributed to the growth of a novel PANI nanoparticle layer and the synergistic effect of CNT/MnO2 nanostructures.
WOS关键词HIGH-PERFORMANCE SUPERCAPACITOR ; MANGANESE OXIDE ; ELECTROCHEMICAL SUPERCAPACITOR ; CARBON NANOTUBES ; GRAPHENE OXIDE ; THIN-FILM ; POLYANILINE ; CAPACITANCE ; WATER ; FABRICATION
WOS研究方向Chemistry ; Physics
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000385175000054
源URL[http://cas-ir.dicp.ac.cn/handle/321008/169880]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Asif, Muhammad; Pan, Lujun
作者单位1.Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
2.Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116024, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116024, Peoples R China
推荐引用方式
GB/T 7714
Rashad, Muhammad,Asif, Muhammad,Tan, Yi,et al. Synthesis of a highly efficient 3D graphene-CNT-MnO2-PANI nanocomposite as a binder free electrode material for supercapacitors[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2016,18(38):26854-26864.
APA Rashad, Muhammad.,Asif, Muhammad.,Tan, Yi.,Pan, Lujun.,Li, Jiayan.,...&Cui, Ruixue.(2016).Synthesis of a highly efficient 3D graphene-CNT-MnO2-PANI nanocomposite as a binder free electrode material for supercapacitors.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,18(38),26854-26864.
MLA Rashad, Muhammad,et al."Synthesis of a highly efficient 3D graphene-CNT-MnO2-PANI nanocomposite as a binder free electrode material for supercapacitors".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 18.38(2016):26854-26864.

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来源:大连化学物理研究所

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