Multifunctional Single-Site Catalysts for Alkoxycarbonylation of Terminal Alkynes
文献类型：期刊论文
| 作者 | Chen, Xingkun1,2; Zhu, Hejun2; Wang, Wenlong2; Du, Hong1,2; Yan, Li2; Wang, Tao1,2; Hu, Xiangping4; Ding, Yunjie2,3 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2016-09-08 |
| 卷号 | 9期号:17页码:2451-2459 |
| 关键词 | Alkoxycarbonylation Multifunctional Catalyst Palladium Porous Organic Polymers Solid Acid |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201600660 |
| 文献子类 | Article |
| 英文摘要 | A multifunctional copolymer (PyPPh2-SO3H@porous organic polymers, POPs) was prepared by combining acidic groups and heterogeneous P,N ligands through the copolymerization of vinyl-functionalized 2-pyridyldiphenylphosphine (2-PyPPh2) and p-styrene sulfonic acid under solvothermal conditions. The morphology and chemical structure of the copolymer were evaluated using a series of characterization techniques. Compared with traditional homogeneous Pd(OAc)(2)/2-PyPPh2/ p-toluenesulfonic acid catalyst, the copolymer supported palladium catalyst (Pd-PyPPh2-SO3H@POPs) exhibited higher activity for alkoxycarbonylation of terminal alkynes under the same conditions. This phenomenon could be attributed to the synergistic effect between the single-site Pd centers, 2-PyPPh2 ligands, and SO3H groups, the outstanding swelling properties as well as the high enrichment of the reactant concentration by the porous catalyst. In addition, the catalyst could be reused at least 4times without any apparent loss of activity. The excellent catalytic reactivity and good recycling properties make it an attractive catalyst for industrial applications. This work paves the way for advanced multifunctional porous organic polymers as a new type of platform for heterogeneous catalysis in the future. |
| WOS关键词 | POROUS ORGANIC POLYMERS ; PALLADIUM COMPLEXES ; HOMOGENEOUS CATALYSIS ; HETEROGENEOUS CATALYSIS ; CARBONYLATION REACTIONS ; IONIC LIQUIDS ; METHOXYCARBONYLATION ; ACID ; HYDROESTERIFICATION ; TRANSESTERIFICATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000383679600026 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169912]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhu, Hejun; Ding, Yunjie |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Xingkun,Zhu, Hejun,Wang, Wenlong,et al. Multifunctional Single-Site Catalysts for Alkoxycarbonylation of Terminal Alkynes[J]. CHEMSUSCHEM,2016,9(17):2451-2459. |
| APA | Chen, Xingkun.,Zhu, Hejun.,Wang, Wenlong.,Du, Hong.,Yan, Li.,...&Ding, Yunjie.(2016).Multifunctional Single-Site Catalysts for Alkoxycarbonylation of Terminal Alkynes.CHEMSUSCHEM,9(17),2451-2459. |
| MLA | Chen, Xingkun,et al."Multifunctional Single-Site Catalysts for Alkoxycarbonylation of Terminal Alkynes".CHEMSUSCHEM 9.17(2016):2451-2459. |
入库方式： OAI收割
来源：大连化学物理研究所
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