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Low-temperature molar heat capacities and thermodynamic properties of a new rare earth complex Er-2(mu (2)-Gly)(6)(H2O)(4)center dot Na-2(ClO4)(8)(H2O)(2)center dot 4H(2)O

文献类型：期刊论文

作者Luo, Guan-Hua1; Gao, Xiao-Han1; Pan, Lu1; Lv, Xue-Chuan1; Tan, Zhi-Cheng2
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
出版日期2016-11-01
卷号126期号:2页码:871-879
关键词Rare Earth Complex Structure Adiabatic Calorimetry Low-temperature Heat Capacity
ISSN号1388-6150
DOI10.1007/s10973-016-5449-z
文献子类Article
英文摘要A hydrous complex of erbium coordinated with glycine sodium perchloric acid, Er-2(mu (2)-Gly)(6)(H2O)(4)center dot Na-2(ClO4)(8)(H2O)(2)center dot 4H(2)O (Gly = glycine), was synthesized firstly and characterized by X-ray single-crystal diffraction. The complex crystallizes centrosymmetrically in the triclinic P-1 space group [a = 9.2959 (5), b = 12.1756 (7) , c = 13.9928 (7) , V = 1367.67 (13) (3), Z = 1]. The low-temperature molar heat capacities and thermodynamic properties of the complex were studied with adiabatic calorimetry. The thermodynamic functions, [H (T)-H (298.15)] and [S (T)-S (298.15)], were derived in the temperature range from 80 to 370 K with a temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric analysis and differential scanning calorimetry.
WOS关键词CONTRAST AGENTS ; LANTHANIDE IONS ; ELECTROLUMINESCENCE
WOS研究方向Thermodynamics ; Chemistry
语种英语
WOS记录号WOS:000385246400053
出版者SPRINGER
源URL[http://cas-ir.dicp.ac.cn/handle/321008/169920]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Lv, Xue-Chuan
作者单位1.Liaoning Shihua Univ, Coll Chem Engn & Environm, Sch Chem & Mat Sci, Fushun 113001, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Luo, Guan-Hua,Gao, Xiao-Han,Pan, Lu,et al. Low-temperature molar heat capacities and thermodynamic properties of a new rare earth complex Er-2(mu (2)-Gly)(6)(H2O)(4)center dot Na-2(ClO4)(8)(H2O)(2)center dot 4H(2)O[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2016,126(2):871-879.
APA Luo, Guan-Hua,Gao, Xiao-Han,Pan, Lu,Lv, Xue-Chuan,&Tan, Zhi-Cheng.(2016).Low-temperature molar heat capacities and thermodynamic properties of a new rare earth complex Er-2(mu (2)-Gly)(6)(H2O)(4)center dot Na-2(ClO4)(8)(H2O)(2)center dot 4H(2)O.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,126(2),871-879.
MLA Luo, Guan-Hua,et al."Low-temperature molar heat capacities and thermodynamic properties of a new rare earth complex Er-2(mu (2)-Gly)(6)(H2O)(4)center dot Na-2(ClO4)(8)(H2O)(2)center dot 4H(2)O".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 126.2(2016):871-879.

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来源：大连化学物理研究所

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