Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins
文献类型：期刊论文
| 作者 | Gao, Shuang1; Dai, Wen; Mi, Yuan; Lv, Ying; Shang, Sensen; Li, Guosong; Chen, Guangwen1 |
| 刊名 | SYNTHESIS-STUTTGART
 |
| 出版日期 | 2016-08-01 |
| 卷号 | 48期号:16页码:2653-2658 |
| 关键词 | Continuous Flow Microreactor Asymmetric Epoxidation Iron Catalysis Electron-deficient Olefins Biomimetic Catalyst |
| ISSN号 | 0039-7881 |
| DOI | 10.1055/s-0035-1561955 |
| 文献子类 | Article |
| 英文摘要 | Asymmetric epoxidation of electron-deficient olefins catalyzed by a biomimetic iron complex in a continuous-flow microreactor is described. The reaction conducted in the microreactor is characterized by rapid (<4 min) epoxidation of trisubstituted enones in high yields (up to 90%) and excellent enantioselectivities (up to 92% ee); compared to its batchwise counterpart, the microreactor reaction also allows shorter reaction times, safer operation, and more precise control over the reaction conditions. |
| WOS关键词 | INSPIRED MANGANESE COMPLEX ; HIGHLY STEREOSELECTIVE EPOXIDATION ; AQUEOUS HYDROGEN-PEROXIDE ; WIDE SUBSTRATE SCOPE ; ENANTIOSELECTIVE EPOXIDATION ; ALPHA,BETA-UNSATURATED KETONES ; CHIRAL KETONES ; CATALYSTS ; ALKENES ; OXIDATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000382509100014 |
| 出版者 | GEORG THIEME VERLAG KG |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170042]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gao, Shuang; Chen, Guangwen |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Shuang,Dai, Wen,Mi, Yuan,et al. Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins[J]. SYNTHESIS-STUTTGART,2016,48(16):2653-2658. |
| APA | Gao, Shuang.,Dai, Wen.,Mi, Yuan.,Lv, Ying.,Shang, Sensen.,...&Chen, Guangwen.(2016).Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins.SYNTHESIS-STUTTGART,48(16),2653-2658. |
| MLA | Gao, Shuang,et al."Development of a Continuous-Flow Microreactor for Asymmetric Epoxidation of Electron-Deficient Olefins".SYNTHESIS-STUTTGART 48.16(2016):2653-2658. |
入库方式： OAI收割
来源：大连化学物理研究所
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