中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol

文献类型:期刊论文

作者Chen, Lei1,2; Lu, Peng1,2; Yuan, Yangyang1; Xu, Li1; Zhang, Xiaomin1; Xu, Lei1
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2016-08-01
卷号37期号:8页码:1381-1388
关键词Nanosized Zsm-22 Zeolite Hydrothermal Synthesis Conversion Of Methanol
ISSN号0253-9837
DOI10.1016/S1872-2067(15)61099-3
文献子类Article
英文摘要ZSM-22 zeolite with different crystal lengths was prepared using a modified hydrothermal method. Rotation speed, Si/Al molar ratio and co-solvent have important effects on the crystal size of ZSM-22. The nanosized zeolite samples were characterized by X-ray diffraction, X-ray fluorescence, nitrogen adsorption, scanning electron microscopy, temperature-programmed desorption of ammonia and solid state nuclear magnetic resonance. The catalytic performance of nanosized ZSM-22 was tested using the conversion of methanol. Compared to conventional ZSM-22, the nanosized ZSM-22 zeolite exhibited superior selectivity to ethylene and aromatics and lower selectivity to propylene. Stability against deactivation was clearly shown by the nanosized ZSM-22 zeolite. A higher external surface area and smaller particle size make this nanosized ZSM-22 zeolite attractive for catalytic applications. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词CONFINED SPACE SYNTHESIS ; DRY-GEL CONVERSION ; ZEOLITE CRYSTALS ; SIZE DISTRIBUTION ; OLEFIN PRODUCTION ; PORE MOUTH ; ISOMERIZATION ; CRYSTALLIZATION ; NANOZEOLITES ; H-ZSM-22
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000381326900024
出版者SCIENCE PRESS
源URL[http://cas-ir.dicp.ac.cn/handle/321008/170044]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Zhang, Xiaomin; Xu, Lei
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Chen, Lei,Lu, Peng,Yuan, Yangyang,et al. Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(8):1381-1388.
APA Chen, Lei,Lu, Peng,Yuan, Yangyang,Xu, Li,Zhang, Xiaomin,&Xu, Lei.(2016).Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol.CHINESE JOURNAL OF CATALYSIS,37(8),1381-1388.
MLA Chen, Lei,et al."Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol".CHINESE JOURNAL OF CATALYSIS 37.8(2016):1381-1388.

入库方式: OAI收割

来源:大连化学物理研究所

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