One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates
文献类型：期刊论文
| 作者 | Wu, Chaoqiang1; Wu, Guojiao1; Zhang, Yan1; Wang, Jianbo1,2 |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2016 |
| 卷号 | 3期号:7页码:817-822 |
| ISSN号 | 2052-4129 |
| DOI | 10.1039/c6qo00141f |
| 文献子类 | Article |
| 英文摘要 | A transition-metal-free method for the synthesis of benzylic boronate esters with arylboronic acids and trimethylsilyldiazomethane (TMSCHN2) has been developed. This transformation is a straightforward homologation of arylboronic acids, which represents a unique approach toward the preparation of pinacol benzylboronates. The reaction has a wide substrate scope and good functional-group tolerance, and it can be scaled up easily. |
| WOS关键词 | IRIDIUM-CATALYZED BORYLATION ; CROSS-COUPLING REACTIONS ; C-H BONDS ; BENZYL HALIDES ; ALKENYLBORONIC ACIDS ; ALKYLBORON COMPOUNDS ; ESTERS ; METAL ; ORGANOBORANES ; BIS(PINACOLATO)DIBORON |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000382496400006 |
| 出版者 | CHINESE CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170066]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,et al. One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(7):817-822. |
| APA | Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,&Wang, Jianbo.(2016).One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates.ORGANIC CHEMISTRY FRONTIERS,3(7),817-822. |
| MLA | Wu, Chaoqiang,et al."One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates".ORGANIC CHEMISTRY FRONTIERS 3.7(2016):817-822. |
入库方式： OAI收割
来源：大连化学物理研究所
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