Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst
文献类型：期刊论文
| 作者 | Ren, Lanhui1,2; Wang, Lianyue2; Lu, Ying2; Li, Guosong2; Gao, Shuang2 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016-08-01 |
| 卷号 | 37期号:8页码:1216-1221 |
| 关键词 | Oxidation Heterogeneous Catalyst Ketone C-h Bond Manganese |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(16)62503-2 |
| 文献子类 | Article |
| 英文摘要 | Novel reusable MnO,-N@C catalyst has been developed for the direct oxidation of N-heterocycles under solvent-free conditions using TBHP as benign oxidant to give the corresponding N-heterocyclic ketones. The catalytic system exhibited a broad substrate scope and excellent regioselectivity, as well as being amenable to gram-scale synthesis. This MnOx-N@C catalyst also showed good reusability and was successfully recycled six times without any significant loss of activity. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | SELECTIVE OXIDATION ; MOLECULAR-OXYGEN ; BENZYLPYRIDINES ; ALCOHOLS |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000381326900004 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170130]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gao, Shuang |
| 作者单位 | 1.Dalian Univ Technol, Coll Chem, Dalian 116024, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Lanhui,Wang, Lianyue,Lu, Ying,et al. Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(8):1216-1221. |
| APA | Ren, Lanhui,Wang, Lianyue,Lu, Ying,Li, Guosong,&Gao, Shuang.(2016).Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst.CHINESE JOURNAL OF CATALYSIS,37(8),1216-1221. |
| MLA | Ren, Lanhui,et al."Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst".CHINESE JOURNAL OF CATALYSIS 37.8(2016):1216-1221. |
入库方式： OAI收割
来源：大连化学物理研究所
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