Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2
文献类型：期刊论文
| 作者 | Zhang, Chaofeng1,2; Wang, Xu3; Li, Mingrun1; Zhang, Zhixin1; Wang, Yehong1; Si, Rui3; Wang, Feng1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 37期号:9页码:1569-1578 |
| 关键词 | Mos2 Coordinative Unsaturated Mo Nitroarene Transfer Hydrogenation Formate Heterogeneous Catalysis |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(16)62504-4 |
| 文献子类 | Article |
| 英文摘要 | We present an efficient approach for the chemoselective synthesis of arylamines from nitroarenes and formate over an oxygen-implanted MoS2 catalyst (O-MoS2). O-MoS2 was prepared by incomplete sulfidation and reduction of an ammonium molybdate precursor. A number of Mo-O bonds were implanted in the as-synthesized ultrathin O-MoS2 nanosheets. As a consequence of the different coordination geometries of O (MoS2) and S (MoS2), and lengths of the Mo-O and Mo-S bonds, the implanted Mo-O bonds induced obvious defects and more coordinatively unsaturated (CUS) Mo sites in O-MoS2, as confirmed by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, high resolution transmission electron microscopy, and extended X-ray absorption fine structure characterization of various MoS2-based materials. O-MoS2 with abundant CUS Mo sites was found to efficiently catalyze the chemoselective reduction of nitroarenes to arylamines. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | AROMATIC NITRO-COMPOUNDS ; ACTIVE EDGE SITES ; SINGLE-ATOM CATALYSTS ; SELECTIVE HYDROGENATION ; FORMIC-ACID ; HYDRAZINE HYDRATE ; GOLD CATALYSTS ; FUNCTIONALIZED NITROARENES ; ULTRATHIN NANOSHEETS ; AZO-COMPOUNDS |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000384156400018 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170140]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Feng |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Chaofeng,Wang, Xu,Li, Mingrun,et al. Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(9):1569-1578. |
| APA | Zhang, Chaofeng.,Wang, Xu.,Li, Mingrun.,Zhang, Zhixin.,Wang, Yehong.,...&Wang, Feng.(2016).Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2.CHINESE JOURNAL OF CATALYSIS,37(9),1569-1578. |
| MLA | Zhang, Chaofeng,et al."Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2".CHINESE JOURNAL OF CATALYSIS 37.9(2016):1569-1578. |
入库方式： OAI收割
来源：大连化学物理研究所
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