Methanol-to-olefin induction reaction over SAPO-34
文献类型：期刊论文
| 作者 | Zhou, You1,2; Qi, Liang1,2; Wei, Yingxu1; Yuan, Cuiyu1; Zhang, Mozhi1,2; Liu, Zhongmin1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 37期号:9页码:1496-1501 |
| 关键词 | Methanol-to-olefin Activation Energy Sapo-34 Hydrocarbon Pool Induction Period |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(15)61110-X |
| 文献子类 | Article |
| 英文摘要 | The methanol-to-olefin induction reaction over the SAPO-34 was performed using a fluidized-bed system. We found that the whole induction period could be divided into three reaction stages. Further investigation of the reaction kinetics revealed that this induction reaction behavior was different from that over H-ZSM-5 catalyst. Compared with the H-ZSM-5, the generation of initial active centers is easier over SAPO-34 because of its limited diffusivity and the spatial confinement effect of the cages. However, the autocatalysis reaction stage is difficult over SAPO-34 because of the continuous formation of inactive methyladamantanes. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | REACTION-MECHANISM ; ZEOLITE H-ZSM-5 ; HYDROCARBON FORMATION ; POOL MECHANISM ; HZSM-5 ZEOLITE ; CO-REACTION ; CONVERSION ; CATALYST ; PERFORMANCE ; SELECTIVITY |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000384156400009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170142]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Zhongmin |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, You,Qi, Liang,Wei, Yingxu,et al. Methanol-to-olefin induction reaction over SAPO-34[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(9):1496-1501. |
| APA | Zhou, You,Qi, Liang,Wei, Yingxu,Yuan, Cuiyu,Zhang, Mozhi,&Liu, Zhongmin.(2016).Methanol-to-olefin induction reaction over SAPO-34.CHINESE JOURNAL OF CATALYSIS,37(9),1496-1501. |
| MLA | Zhou, You,et al."Methanol-to-olefin induction reaction over SAPO-34".CHINESE JOURNAL OF CATALYSIS 37.9(2016):1496-1501. |
入库方式： OAI收割
来源：大连化学物理研究所
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