Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones
文献类型：期刊论文
| 作者 | Qi, Zisong; Li, Xingwei; Kong, Lingheng |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-09-02 |
| 卷号 | 18期号:17页码:4392-4395 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.6b02146 |
| 文献子类 | Article |
| 英文摘要 | Vinyl benzoxazinanone was applied as an electrophilic allylating reagent for a series of arenes under redox-neutral Rh(III) catalysis. This reaction occurs in high efficiency under mild conditions to afford allylarenes bearing a sulfonamide functionality in exclusively E-selectivity. This allylation system combines C-H activation of arenes and scission of an unstrained six-membered ring. |
| WOS关键词 | ELECTRON-DEFICIENT POLYFLUOROARENES ; FRIEDEL-CRAFTS ALKYLATION ; BOND ACTIVATION ; SELECTIVE ALLYLATION ; ALLYLIC CARBONATES ; RHODIUM CATALYSIS ; ROOM-TEMPERATURE ; MILD ; FUNCTIONALIZATION ; ALCOHOLS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000382711200062 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170214]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Zisong,Li, Xingwei,Kong, Lingheng. Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones[J]. ORGANIC LETTERS,2016,18(17):4392-4395. |
| APA | Qi, Zisong,Li, Xingwei,&Kong, Lingheng.(2016).Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones.ORGANIC LETTERS,18(17),4392-4395. |
| MLA | Qi, Zisong,et al."Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones".ORGANIC LETTERS 18.17(2016):4392-4395. |
入库方式： OAI收割
来源：大连化学物理研究所
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