Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis
文献类型：期刊论文
| 作者 | Zhou, Xukai1; Yu, Songjie1; Tang, Guodong1; Li, Yingzi2; Lan, Yu2; Li, Xingwei1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-07-18 |
| 卷号 | 55期号:30页码:8696-8700 |
| 关键词 | Amination Arenes C-h Activation Reaction Mechanisms Rhodium |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201602224 |
| 文献子类 | Article |
| 英文摘要 | Previous direct C-H nitrogenation suffered from simple amidation/amination with limited atom-economy and is mostly limited to C(sp(2))-H substrates. In this work, anthranil was designed as a novel bifunctional aminating reagent for both C(sp(2)) H and C(sp(3)) H bonds under rhodium(III) catalysis, thus affording a nucleophilic aniline tethered to an electrophilic carbonyl. A tridendate rhodium(III) complex has been isolated as the resting state of the catalyst, and DFT studies established the intermediacy of a nitrene species. |
| WOS关键词 | C-H AMINATION ; CARBON-NITROGEN BONDS ; INTERMOLECULAR AMIDATION ; COUPLING REACTIONS ; INTRAMOLECULAR C(SP(3))-H ; ROOM-TEMPERATURE ; ACTIVATION ; AZIDES ; ALKYNES ; ARENES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000383253500038 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170218]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lan, Yu; Li, Xingwei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xukai,Yu, Songjie,Tang, Guodong,et al. Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(30):8696-8700. |
| APA | Zhou, Xukai,Yu, Songjie,Tang, Guodong,Li, Yingzi,Lan, Yu,&Li, Xingwei.(2016).Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(30),8696-8700. |
| MLA | Zhou, Xukai,et al."Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp(3))-H and C(sp(2))-H under Rhodium(III) Catalysis".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.30(2016):8696-8700. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。