Anion exchange membranes with well-defined ion transporting nanochannels via self-assembly of polymerizable ionic liquids
文献类型：期刊论文
| 作者 | Dong, Bin2; Wu, Aoli1; Sun, Na1; Zheng, Liqiang1; Gao, Xinpei1; Lu, Fei1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:34页码:13316-13323 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c6ta05223a |
| 文献子类 | Article |
| 英文摘要 | In this study, we present a facile method to construct highly ordered and well-defined ionic channels in anion-exchange membranes (AEMs) through in-phase photopolymerization of liquid crystals (LCs). Hexagonal and lamellar LC samples were prepared by the self-organization of polymerizable amphiphilic imidazolium-based ionic liquids. The preservation of LC nanostructures in the obtained polymeric membranes was confirmed by the combination of small-angle X-ray scattering (SAXS), polarized optical microscope (POM), and scanning electronic microscopy (SEM) measurements. Phase separations of LCs at the molecular level provided highly ordered and well-defined ionic channels for efficient anion conduction and meanwhile maintained a strong hydrophobic domain to suppress the swelling degree. The membranes synthesized in the present work provide a promising model system for understanding the idea of constructing ionic highways in AEMs through self-organization. |
| WOS关键词 | ELECTROLYTE FUEL-CELLS ; CLICK CHEMISTRY ; PERFORMANCE ; CRYSTALS ; ENHANCEMENT ; STABILITY ; PATHWAYS ; PROPERTY ; AMMONIUM ; HIGHWAY |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000382110200036 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170220]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zheng, Liqiang |
| 作者单位 | 1.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Bin,Wu, Aoli,Sun, Na,et al. Anion exchange membranes with well-defined ion transporting nanochannels via self-assembly of polymerizable ionic liquids[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(34):13316-13323. |
| APA | Dong, Bin,Wu, Aoli,Sun, Na,Zheng, Liqiang,Gao, Xinpei,&Lu, Fei.(2016).Anion exchange membranes with well-defined ion transporting nanochannels via self-assembly of polymerizable ionic liquids.JOURNAL OF MATERIALS CHEMISTRY A,4(34),13316-13323. |
| MLA | Dong, Bin,et al."Anion exchange membranes with well-defined ion transporting nanochannels via self-assembly of polymerizable ionic liquids".JOURNAL OF MATERIALS CHEMISTRY A 4.34(2016):13316-13323. |
入库方式： OAI收割
来源：大连化学物理研究所
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