Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose
文献类型：期刊论文
| 作者 | Huber, George W.3; Li, Ning1,4; Zhang, Tao1,4; Wang, Aiqin1,4; Sheng, Xueru1,2; Li, Guangyi1; Wang, Wentao1; Cong, Yu1; Wang, Xiaodong1 |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2016-08-01 |
| 卷号 | 62期号:8页码:2754-2761 |
| 关键词 | Lignocellulose High Density Aviation Fuel Aldol Condensation Hydrodeoxygenation Dual-bed Continuous Flow Reactor |
| ISSN号 | 0001-1541 |
| DOI | 10.1002/aic.15248 |
| 文献子类 | Article |
| 英文摘要 | In this article, we demonstrated an integrated process for the direct production of tri(cyclopentane) with cyclopentanone which can be obtained from lignocellulose. The reaction was carried out in a dual-bed continuous flow reactor. In the first bed, cyclopentanone was selectively converted to 2,5-dicyclopentylcyclopentanol over the Pd-MgAl-HT (hydrotalcite) catalyst. Under solvent-free and mild conditions (443 K, 0.1 MPa H-2), high carbon yield (81.2%) of 2,5-dicyclopentylcyclopentanol was achieved. Subsequently, the 2,5-dicyclopentylcyclopentanol was further hydrodeoxygenated to tri(cyclopentane) in the second bed. Among the investigated catalysts, the Ni-H beta-DP prepared by deposition-precipitation (DP) method exhibited the highest activity for the hydrodeoxygenation step. By using Pd-MgAl-HT as the first bed catalyst and Ni-HbDP as the second bed catalyst, tri(cyclopentane) was directly produced at high carbon yield (80.0%) with cyclopentanone as feedstock. This polycycloalkane has high density (0.91 kg/L) and can be used as additive to improve the density and volumetric heating value of bio-jet fuel. (C) 2016 American Institute of Chemical Engineers |
| WOS关键词 | HIGH-QUALITY DIESEL ; SELECTIVE HYDROGENATION ; TRANSPORTATION FUELS ; BIMETALLIC CATALYSTS ; BIODIESEL PRODUCTION ; SINGLE-REACTOR ; LIQUID ALKANES ; RANGE ALKANES ; BIOMASS ; CONVERSION |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000382986000014 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170222]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Ning; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China 3.Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA 4.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huber, George W.,Li, Ning,Zhang, Tao,et al. Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose[J]. AICHE JOURNAL,2016,62(8):2754-2761. |
| APA | Huber, George W..,Li, Ning.,Zhang, Tao.,Wang, Aiqin.,Sheng, Xueru.,...&Wang, Xiaodong.(2016).Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose.AICHE JOURNAL,62(8),2754-2761. |
| MLA | Huber, George W.,et al."Dual-Bed Catalyst System for the Direct Synthesis of High Density Aviation Fuel with Cyclopentanone from Lignocellulose".AICHE JOURNAL 62.8(2016):2754-2761. |
入库方式： OAI收割
来源：大连化学物理研究所
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