Bimetallic Pt-Sn/gamma-Al2O3 catalyzed beta-alkylation of secondary alcohols with primary alcohols under solvent-free conditions
文献类型：期刊论文
| 作者 | Yu, Zhengkun; Wu, Kaikai; He, Wei; Sun, Chenglin |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2016-09-07 |
| 卷号 | 57期号:36页码:4017-4020 |
| 关键词 | Alcohols Beta-alkylation C-c Bond Formation Hydrogen Borrowing Pt-sn Catalyst |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2016.07.037 |
| 文献子类 | Article |
| 英文摘要 | Heterogeneous bimetallic Pt-Sn/gamma-Al2O3 (0.5 wt% Pt, molar ratio Pt:Sn = 1:3) was successfully utilized as the catalyst for direct beta-alkylation of secondary alcohols with primary alcohols under solvent-free conditions. beta-Alkylated secondary alcohols were obtained in moderate to high yields with water formed as the by-product through a hydrogen borrowing pathway. The present protocol provides a concise atom-economical and environmentally benign method for C-C bond formation. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS关键词 | BORROWING HYDROGEN METHODOLOGY ; TERTIARY-AMINES ; METHYL KETONES ; N-ALKYLATION ; C-ALKYLATION ; DEHYDROGENATION ; EFFICIENT ; IRIDIUM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000382338200008 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170236]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhengkun |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Zhengkun,Wu, Kaikai,He, Wei,et al. Bimetallic Pt-Sn/gamma-Al2O3 catalyzed beta-alkylation of secondary alcohols with primary alcohols under solvent-free conditions[J]. TETRAHEDRON LETTERS,2016,57(36):4017-4020. |
| APA | Yu, Zhengkun,Wu, Kaikai,He, Wei,&Sun, Chenglin.(2016).Bimetallic Pt-Sn/gamma-Al2O3 catalyzed beta-alkylation of secondary alcohols with primary alcohols under solvent-free conditions.TETRAHEDRON LETTERS,57(36),4017-4020. |
| MLA | Yu, Zhengkun,et al."Bimetallic Pt-Sn/gamma-Al2O3 catalyzed beta-alkylation of secondary alcohols with primary alcohols under solvent-free conditions".TETRAHEDRON LETTERS 57.36(2016):4017-4020. |
入库方式： OAI收割
来源：大连化学物理研究所
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