CO2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity
文献类型：期刊论文
| 作者 | Yang, Xiaofang1; Kattel, Shyam1; Yu, Weiting2; Yan, Binhang1; Huang, Yanqiang3; Wan, Weiming2; Liu, Ping1; Chen, Jingguang G.1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-07-04 |
| 卷号 | 55期号:28页码:7968-7973 |
| 关键词 | Bimetallic Catalysts Carbon Dioxide Heterogeneous Catalysis Hydrogenation Supported Catalysts |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201601661 |
| 文献子类 | Article |
| 英文摘要 | By simply changing the oxide support, the selectivity of a metal-oxide catalysts can be tuned. For the CO2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO2, ZrO2, and TiO2), replacing a TiO2 support by CeO2 or ZrO2 selectively strengthens the binding of C, O-bound and O-bound species at the PtCo-oxide interface, leading to a different product selectivity. These results reveal mechanistic insights into how the catalytic performance of metal-oxide catalysts can be fine-tuned. |
| WOS关键词 | FISCHER-TROPSCH SYNTHESIS ; TOTAL-ENERGY CALCULATIONS ; WAVE BASIS-SET ; HETEROGENEOUS CATALYSTS ; SURFACE-CHEMISTRY ; METHANOL ; REDUCTION ; AU ; CONVERSION ; INTERFACE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000383253100012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170264]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Ping; Chen, Jingguang G. |
| 作者单位 | 1.Brookhaven Natl Lab, Dept Chem, 2 Ctr St, Upton, NY 11973 USA 2.Columbia Univ, Dept Chem Engn, 1500 W 120th St, New York, NY 10027 USA 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xiaofang,Kattel, Shyam,Yu, Weiting,et al. CO2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(28):7968-7973. |
| APA | Yang, Xiaofang.,Kattel, Shyam.,Yu, Weiting.,Yan, Binhang.,Huang, Yanqiang.,...&Chen, Jingguang G..(2016).CO2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(28),7968-7973. |
| MLA | Yang, Xiaofang,et al."CO2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.28(2016):7968-7973. |
入库方式： OAI收割
来源：大连化学物理研究所
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