Highly active Ag clusters stabilized on TiO2 nanocrystals for catalytic reduction of p-nitrophenol
文献类型：期刊论文
| 作者 | Wang, Xin1,3; Zhao, Zhe1; Ou, Dingrong1; Tu, Baofeng1; Cui, Daan1; Wei, Xuming2; Cheng, Mojie1 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2016-11-01 |
| 卷号 | 385页码:445-452 |
| 关键词 | Ag/tio2 Nanocomposites Ag Clusters Tio2 Nanocrystal Silver Mirror Reaction P-nitrophenol |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2016.05.147 |
| 文献子类 | Article |
| 英文摘要 | Ag/TiO2 nanocomposites comprising of Ag clusters on TiO2 nanocrystal surfaces are of great significance in catalysts and advanced functional materials. Herein a novel method to synthesize Ag/TiO2 nanocomposites with Ag clusters under 2 nm on TiO2 nanocrystal surfaces have been developed. The success of this method relies on a silver mirror reaction in toluene, which refers to the reduction of silver-dodecylamine complexes by acetaldehyde in the presence of mono-dispersed TiO2 nanocrystals. The prepared Ag/TiO2 nanocomposites have been characterized by FT-IR spectra, UV-vis absorption spectra, X-ray diffraction (XRD) analysis, ultra high resolution scanning electron microscope (Ultra-HRSEM), high resolution transmission electron microscope (HRTEM) and X-ray photoelectron spectra (XPS). Catalytic activity of Ag/TiO2 nanocomposites is evaluated for the reduction of p-nitrophenol (4-NP) into p-aminophenol (4-AP) by NaBH4. Results demonstrate that Ag/TiO2 nanocomposites have shown an outstanding catalytic activity as well as a good stability in successive reduction of 4-NP. Noticeably, TOF of Ag/TiO2-0.75 nanocomposites obtained in this work is the highest among Ag based catalysts previously reported. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | SILVER NANOPARTICLES ; GREEN SYNTHESIS ; PALLADIUM NANOPARTICLES ; AU NANOPARTICLES ; 4-NITROPHENOL ; OXIDE ; GRAPHENE ; GOLD ; SIZE ; HYDROGENATION |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000380825900053 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170316]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Cheng, Mojie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cells, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xin,Zhao, Zhe,Ou, Dingrong,et al. Highly active Ag clusters stabilized on TiO2 nanocrystals for catalytic reduction of p-nitrophenol[J]. APPLIED SURFACE SCIENCE,2016,385:445-452. |
| APA | Wang, Xin.,Zhao, Zhe.,Ou, Dingrong.,Tu, Baofeng.,Cui, Daan.,...&Cheng, Mojie.(2016).Highly active Ag clusters stabilized on TiO2 nanocrystals for catalytic reduction of p-nitrophenol.APPLIED SURFACE SCIENCE,385,445-452. |
| MLA | Wang, Xin,et al."Highly active Ag clusters stabilized on TiO2 nanocrystals for catalytic reduction of p-nitrophenol".APPLIED SURFACE SCIENCE 385(2016):445-452. |
入库方式： OAI收割
来源：大连化学物理研究所
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