Synthesis of core/shell structured Pd3Au@Pt/C with enhanced electrocatalytic activity by regioselective atomic layer deposition combined with a wet chemical method
文献类型：期刊论文
| 作者 | Liu, Huiyuan2,3,4; Song, Yujiang3; Li, Shushuang2; Li, Jia3; Liu, Yuan1,2; Jiang, Ying-Bing5; Guo, Xinwen3 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:71页码:66712-66720 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra04990g |
| 文献子类 | Article |
| 英文摘要 | We report the synthesis of Pd3Au@Pt/C by atomic layer deposition (ALD) combined with a wet chemical method. Initially, nearly uniform Pd3Au nanoparticles (NPs) (similar to 4.7 nm) supported on carbon with a loading of similar to 20 wt% were prepared by reducing metal complexes confined in reverse micelles adsorbed on carbon. Next, a Pt thin layer (less than 1 nm) was selectively deposited on purified Pd3Au particles instead of on carbon by regioselective ALD that likely arises from the coverage of nucleation sites on carbon by surfactant molecules in conjunction with catalytic decomposition of the Pt precursor on Pd3Au. The resulting core-shell structured material was subject to TEM, HAADF-STEM/EDX, XRD, XPS and electrochemical measurements. Interestingly, Pd3Au@Pt/C demonstrates a significantly improved electrocatalytic activity toward both formic acid oxidation reaction (FAOR) and oxygen reduction reaction (ORR) compared with Pd3Au/C and state-of-the art Pt/C. This study opens up a unique avenue for the synthesis core/shell structured materials with potential applications in catalysis, electrocatalysis, and so on. |
| WOS关键词 | OXYGEN REDUCTION REACTION ; CORE-SHELL NANOPARTICLES ; PLATINUM-MONOLAYER SHELL ; FUEL-CELLS ; PERFORMANCE ; CATALYSTS ; NANOCATALYSTS ; STABILITY ; HYDROGEN ; DESIGN |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000380353600040 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170340]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Song, Yujiang |
| 作者单位 | 1.Chinese Acad Sci, CIGIT, Chongqing 400714, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Labs Clean Energy, Dalian 116023, Liaoning, Peoples R China 3.Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 5.Univ New Mexico, Dept Earth & Planetary Sci, Albuquerque, NM 87131 USA |
| 推荐引用方式 GB/T 7714 | Liu, Huiyuan,Song, Yujiang,Li, Shushuang,et al. Synthesis of core/shell structured Pd3Au@Pt/C with enhanced electrocatalytic activity by regioselective atomic layer deposition combined with a wet chemical method[J]. RSC ADVANCES,2016,6(71):66712-66720. |
| APA | Liu, Huiyuan.,Song, Yujiang.,Li, Shushuang.,Li, Jia.,Liu, Yuan.,...&Guo, Xinwen.(2016).Synthesis of core/shell structured Pd3Au@Pt/C with enhanced electrocatalytic activity by regioselective atomic layer deposition combined with a wet chemical method.RSC ADVANCES,6(71),66712-66720. |
| MLA | Liu, Huiyuan,et al."Synthesis of core/shell structured Pd3Au@Pt/C with enhanced electrocatalytic activity by regioselective atomic layer deposition combined with a wet chemical method".RSC ADVANCES 6.71(2016):66712-66720. |
入库方式： OAI收割
来源：大连化学物理研究所
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