Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction
文献类型：期刊论文
| 作者 | Leng, Wenguang2; Peng, Yongsheng2; Zhang, Jianqiang2; Lu, Hui2; Feng, Xiao1; Ge, Rile2; Dong, Bin2; Wang, Bo1; Hu, Xiangping2; Gao, Yanan2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016-06-27 |
| 卷号 | 22期号:27页码:9087-9091 |
| 关键词 | Cascade Reactions Covalent Organic Frameworks Heterogeneous Catalysis Metal Loading Nitrogen Ligands |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201601334 |
| 文献子类 | Article |
| 英文摘要 | Precise control of the number and position of the catalytic metal ions in heterogeneous catalysts remains a big challenge. Here we synthesized a series of two-dimensional (2D) covalent organic frameworks (COFs) containing two different types of nitrogen ligands, namely imine and bipyridine, with controllable contents. For the first time, the selective coordination of the two nitrogen ligands of the 2D COFs to two different metal complexes, chloro(1,5-cyclooctadiene)rhodium(I) (Rh(COD) Cl) and palladium(II) acetate (Pd(OAc)(2)), has been realized using a programmed synthetic procedure. The bimetallically docked COFs showed excellent catalytic activity in a one-pot addition-oxidation cascade reaction. The high surface area, controllable metal-loading content, and predesigned active sites make them ideal candidates for their use as heterogeneous catalysts in a wide range of chemical reactions. |
| WOS关键词 | STORAGE ; CATALYSIS ; HYDROGEN ; COMPLEXES ; POLYMERS ; LIGANDS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000380271100009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170346]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gao, Yanan |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem, Key Lab Cluster Sci, Minist Educ China, 5 South Zhongguancun St, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Leng, Wenguang,Peng, Yongsheng,Zhang, Jianqiang,et al. Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(27):9087-9091. |
| APA | Leng, Wenguang.,Peng, Yongsheng.,Zhang, Jianqiang.,Lu, Hui.,Feng, Xiao.,...&Gao, Yanan.(2016).Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction.CHEMISTRY-A EUROPEAN JOURNAL,22(27),9087-9091. |
| MLA | Leng, Wenguang,et al."Sophisticated Design of Covalent Organic Frameworks with Controllable Bimetallic Docking for a Cascade Reaction".CHEMISTRY-A EUROPEAN JOURNAL 22.27(2016):9087-9091. |
入库方式： OAI收割
来源：大连化学物理研究所
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