Ammonium Aminodiboranate: A Long-Sought Isomer of Diammoniate of Diborane and Ammonia Borane Dimer
文献类型：期刊论文
| 作者 | Chen, Weidong1,6; Yu, Haibo2; Wu, Guotao6; He, Teng6; Li, Zhao1,6; Guo, Zaiping3; Liu, Huakun3; Huang, Zhenguo3; Chen, Ping4,5,6 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016-06-01 |
| 卷号 | 22期号:23页码:7727-7729 |
| 关键词 | Aminodiboranes Boranes Boron Hydrogen Bonds |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201601375 |
| 文献子类 | Article |
| 英文摘要 | Ammonium minodiboranate ([NH4] [BH3NH2BH3]) is a long-sought isomer of diammoniate of diborane ([NH3BH2NH3][BH4]) and ammonia borane (NH3BH3) dimer. Our results show that [NH4][BH3NH2BH3] is stable in tetrahydrofuran at -18 degrees C and decomposes rapidly to NH3BH2NH2BH3 and H-2 at elevated temperatures. The decomposition pathway is dictated by the dihydrogen bonding between H delta+ on NH4+ and H delta- on BH3, as confirmed by theoretical calculations. This is in contrast to the interconversion between [NH3BH2NH3][BH4] and (NH3BH3)(2), although all three have dihydrogen bonds and the same stoichiometry. |
| WOS关键词 | INORGANIC BUTANE ANALOG ; CHEMICAL EVIDENCE ; BOROHYDRIDE ; NH3BH2NH2BH3 ; EVOLUTION ; HYDROGEN ; HYDRIDES ; RELEASE ; SODIUM ; SALTS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000380267100009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170348]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Huang, Zhenguo; Chen, Ping |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia 3.Univ Wollongong, ISEM, Wollongong, NSW 2522, Australia 4.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat IChEM, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 5.Chinese Acad Sci, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 6.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Weidong,Yu, Haibo,Wu, Guotao,et al. Ammonium Aminodiboranate: A Long-Sought Isomer of Diammoniate of Diborane and Ammonia Borane Dimer[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(23):7727-7729. |
| APA | Chen, Weidong.,Yu, Haibo.,Wu, Guotao.,He, Teng.,Li, Zhao.,...&Chen, Ping.(2016).Ammonium Aminodiboranate: A Long-Sought Isomer of Diammoniate of Diborane and Ammonia Borane Dimer.CHEMISTRY-A EUROPEAN JOURNAL,22(23),7727-7729. |
| MLA | Chen, Weidong,et al."Ammonium Aminodiboranate: A Long-Sought Isomer of Diammoniate of Diborane and Ammonia Borane Dimer".CHEMISTRY-A EUROPEAN JOURNAL 22.23(2016):7727-7729. |
入库方式： OAI收割
来源：大连化学物理研究所
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