Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis
文献类型：期刊论文
| 作者 | Zhou, Yan; Li, Yong; Shen, Wenjie |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2016-05-20 |
| 卷号 | 11期号:10页码:1470-1488 |
| 关键词 | Heterogeneous Catalysis Metal-support Interactions Nanoparticles Shape Engineering Supported Catalysts |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201600115 |
| 文献子类 | Review |
| 英文摘要 | The fabrication of oxide particles with tunable sizes and shapes at the nanoscale is one of the most crucial issues for the design and development of highly efficient heterogeneous catalysts. The shape of oxide nanoparticles has been demonstrated to affect their catalytic properties remarkably. Tuning the shape of oxide particles allows preferential exposure of specific reactive facets; this can maximize the number of active sites available to the reactants, which can improve the activity and also mediate the reaction route to a specific channel to achieve higher selectivity for a particular chemical reaction. In addition, the shape of the oxide particles affects their interaction with metal particles or clusters, and this involves interfacial strain and charge transfer. Metal particles or clusters dispersed on the reactive or polar facets of the oxide support often provide superior catalytic performance, primarily because of strong metal-support interactions. However, the geometric and electronic features of the metal-oxide interface may change during the course of the reaction, induced by chemisorption of reactive molecules at elevated temperatures, which should be taken into account in proposing a structure-reactivity relationship. |
| WOS关键词 | WATER-GAS SHIFT ; METAL-SUPPORT INTERACTION ; TEMPERATURE CO OXIDATION ; DENSITY-FUNCTIONAL THEORY ; DEFINED SURFACE PLANES ; CEO2 NANOCRYSTALS ; IN-SITU ; GOLD NANOPARTICLES ; METHANOL SYNTHESIS ; AU NANOPARTICLES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000379518200001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170394]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Shen, Wenjie |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Yan,Li, Yong,Shen, Wenjie. Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(10):1470-1488. |
| APA | Zhou, Yan,Li, Yong,&Shen, Wenjie.(2016).Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis.CHEMISTRY-AN ASIAN JOURNAL,11(10),1470-1488. |
| MLA | Zhou, Yan,et al."Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis".CHEMISTRY-AN ASIAN JOURNAL 11.10(2016):1470-1488. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。