Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent
文献类型：期刊论文
| 作者 | Zhang, Miao1,2; Liu, Lin1; He, Teng1; Wu, Guotao1; Chen, Ping1 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2016-06-21 |
| 卷号 | 11期号:12页码:1849-1855 |
| 关键词 | 2d Carbonaceous Polymer Nanosheets Carbon Dioxide Capture Ionothermal Method Microporous Materials Polymers |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201600396 |
| 文献子类 | Article |
| 英文摘要 | The synthesis of two-dimensional (2D) polymer nanosheets with a well-defined microporous structure remains challenging in materials science. Here, a new kind of 2D microporous carbonaceous polymer nanosheets was synthesized through polymerization of a very low concentration of 1,4-dicyanobenzene in molten zinc chloride at 400-500 degrees C. This type of nanosheets has a thickness in the range of 3-20nm, well-defined microporosity, a high surface area (approximate to 537m(2)g(-1)), and a large micropore volume (approximate to 0.45cm(3)g(-1)). The microporous carbonaceous polymer nanosheets exhibit superior CO2 sorption capability (8.14wt% at 298K and 1bar) and a relatively high CO2 selectivity toward N-2 (25.6). Starting from different aromatic nitrile monomers, a variety of 2D carbonaceous polymer nanosheets can be obtained showing a certain universality of the ionothermal method reported herein. |
| WOS关键词 | COVALENT ORGANIC FRAMEWORKS ; TRIAZINE-BASED FRAMEWORKS ; ON-SURFACE SYNTHESIS ; IONOTHERMAL SYNTHESIS ; DIOXIDE CAPTURE ; THIN-FILMS ; AIR/WATER INTERFACE ; LARGE-AREA ; GRAPHENE ; CAPACITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000379519400016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170410]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Lin; Chen, Ping |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Miao,Liu, Lin,He, Teng,et al. Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(12):1849-1855. |
| APA | Zhang, Miao,Liu, Lin,He, Teng,Wu, Guotao,&Chen, Ping.(2016).Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent.CHEMISTRY-AN ASIAN JOURNAL,11(12),1849-1855. |
| MLA | Zhang, Miao,et al."Synthesis of Two-dimensional Microporous Carbonaceous Polymer Nanosheets and Their Application as High-performance CO2 Capture Sorbent".CHEMISTRY-AN ASIAN JOURNAL 11.12(2016):1849-1855. |
入库方式： OAI收割
来源：大连化学物理研究所
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