Hybrid polymer matrix composite containing polyaniline and Nafion as novel precursor of the enhanced catalyst for oxygen reduction reaction
文献类型：期刊论文
| 作者 | Fu, Xudong1,2; Wang, Suli1; Li, Huanqiao1; Xia, Zhangxun1; Jiang, Luhua1; Sun, Gongquan1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:65页码:59961-59969 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra08654c |
| 文献子类 | Article |
| 英文摘要 | A hybrid polymer matrix composite has been synthesized by in situ polymerization of aniline monomers into Nafion framework and characterized by X-ray diffraction and thermo-gravimetric analysis, which serves as a novel nitrogen precursor for metal-nitrogen-doped carbon catalyst. The electrostatic interaction between the amino groups of polyaniline and sulfonate groups of Nafion is found to be helpful for the promotion of thermal stability of the nitrogen precursor, which increases the nitrogen content of the catalyst. High specific surface area can be achieved via the decomposition and volatilization of Nafion in the pyrolysis procedure. The half-wave potential of the Nfn/PA/Fe-2 catalyst is 0.879 V, larger than that of the commercial Pt/C catalyst (E-1/2 = 0.860 V). After 5000 cycles in alkaline media, the half-wave potential of Nfn/PA/Fe-2 decreases by 19 mV, which exhibits the excellent electrochemical durability and promising application in fields of metal-air batteries and alkaline fuel cells. |
| WOS关键词 | NITROGEN-DOPED GRAPHENE ; HIGH ELECTROCATALYTIC ACTIVITY ; THERMAL-STABILITY ; FUEL-CELLS ; CARBON NANOSHEETS ; FE/N/C CATALYSTS ; ALKALINE MEDIA ; PERFORMANCE ; SULFUR ; PYROLYSIS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000379351600010 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170434]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Sun, Gongquan |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Zhongshan Rd 457, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Xudong,Wang, Suli,Li, Huanqiao,et al. Hybrid polymer matrix composite containing polyaniline and Nafion as novel precursor of the enhanced catalyst for oxygen reduction reaction[J]. RSC ADVANCES,2016,6(65):59961-59969. |
| APA | Fu, Xudong,Wang, Suli,Li, Huanqiao,Xia, Zhangxun,Jiang, Luhua,&Sun, Gongquan.(2016).Hybrid polymer matrix composite containing polyaniline and Nafion as novel precursor of the enhanced catalyst for oxygen reduction reaction.RSC ADVANCES,6(65),59961-59969. |
| MLA | Fu, Xudong,et al."Hybrid polymer matrix composite containing polyaniline and Nafion as novel precursor of the enhanced catalyst for oxygen reduction reaction".RSC ADVANCES 6.65(2016):59961-59969. |
入库方式： OAI收割
来源：大连化学物理研究所
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