The influence of impregnation sequence on glycerol hydrogenolysis over iridium-rhenium catalyst
文献类型：期刊论文
| 作者 | Luo, Wenting1,2; Lyu, Yuan1; Gong, Leifeng1; Du, Hong1,2; Jiang, Miao1,2; Ding, Yunjie1,3 |
| 刊名 | REACTION KINETICS MECHANISMS AND CATALYSIS
 |
| 出版日期 | 2016-08-01 |
| 卷号 | 118期号:2页码:481-496 |
| 关键词 | Glycerol Hydrogenolysis Iridium Rhenium 1 3-propanediol |
| ISSN号 | 1878-5190 |
| DOI | 10.1007/s11144-016-0975-z |
| 文献子类 | Article |
| 英文摘要 | A series of iridium-rhenium catalysts with different impregnation sequences were prepared and the catalytic properties of these catalysts for glycerol hydrogenolysis were evaluated. The catalyst prepared by the impregnation of Ir prior to Re afforded the best selectivity to 1,3-propanediol of 49.2 % with 43.7 % glycerol conversion. These catalysts were also characterized by temperature programmed reduction (TPR), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), NH3-temperature programmed desorption (NH3-TPD), Fourier transform infrared spectroscopy (FT-IR) and H-2-chemisorption. It was found that Ir-0 species played a key role on the activities of glycerol conversion, and Re species might act as an efficient promoter to improve the dispersive state of Ir species as well as the reducibility. Kinetic studies have also been conducted and it was observed that the number of Ir-0 may affect the extent of consecutive hydrogenolysis of 1,3-propanediol over catalysts, and an appropriate number of Ir-0 was of importance to 1,3-propanediol selectivity. |
| WOS关键词 | SELECTIVE HYDROGENOLYSIS ; OXIDE CATALYSTS ; RE CATALYSTS ; 1,3-PROPANEDIOL ; IR-REOX/SIO2 ; PERFORMANCE ; METHANOL ; SOLVENT ; SURFACE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000379345000010 |
| 出版者 | SPRINGER |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170438]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Ding, Yunjie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Wenting,Lyu, Yuan,Gong, Leifeng,et al. The influence of impregnation sequence on glycerol hydrogenolysis over iridium-rhenium catalyst[J]. REACTION KINETICS MECHANISMS AND CATALYSIS,2016,118(2):481-496. |
| APA | Luo, Wenting,Lyu, Yuan,Gong, Leifeng,Du, Hong,Jiang, Miao,&Ding, Yunjie.(2016).The influence of impregnation sequence on glycerol hydrogenolysis over iridium-rhenium catalyst.REACTION KINETICS MECHANISMS AND CATALYSIS,118(2),481-496. |
| MLA | Luo, Wenting,et al."The influence of impregnation sequence on glycerol hydrogenolysis over iridium-rhenium catalyst".REACTION KINETICS MECHANISMS AND CATALYSIS 118.2(2016):481-496. |
入库方式： OAI收割
来源：大连化学物理研究所
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