Synthesis of Bis(hydroxylmethylfurfuryl)amine Monomers from 5-Hydroxymethylfurfural
文献类型：期刊论文
| 作者 | Xu, Zhanwei; Yan, Peifang; Liu, Kairui; Wan, Lu; Xu, Wenjuan; Li, Huixiang; Liu, Xiumei; Zhang, Z. Conrad |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2016-06-08 |
| 卷号 | 9期号:11页码:1255-1258 |
| 关键词 | Biomass Green Chemistry Polymers Renewable Resources Ruthenium |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201600122 |
| 文献子类 | Article |
| 英文摘要 | We report the synthesis of bis(hydroxylmethylfurfuryl)amine (BHMFA) from 5-hydroxymethylfurfural (5-HMF) by reacting 5-HMF with primary amines in the presence of homogeneous Ru-II catalysts having sterically strained ligands. BHMFA is a group of furan-based monomers that offer great potential to form functional biopolymers with tunable properties. A range of primary amines, such as aliphatic and benzyl amines, are readily converted with 5-HMF to form the corresponding BHMFA in good yields. The reaction proceeds through reductive amination of 5-HMF with primary amine to form secondary amine, followed by reductive amination of 5-HMF with insitu generated secondary amine to produce BHMFA. |
| WOS关键词 | MONONUCLEAR RUTHENIUM(II) COMPLEXES ; RENEWABLE RESOURCES ; 2,5-FURANDICARBOXYLIC ACID ; BIOFUEL 2,5-DIMETHYLFURAN ; LIGNOCELLULOSIC BIOMASS ; CATALYTIC CONVERSION ; GAMMA-VALEROLACTONE ; FURAN POLYMERS ; LEVULINIC ACID ; BUILDING-BLOCK |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000378633800004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170466]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Z. Conrad |
| 作者单位 | Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Zhanwei,Yan, Peifang,Liu, Kairui,et al. Synthesis of Bis(hydroxylmethylfurfuryl)amine Monomers from 5-Hydroxymethylfurfural[J]. CHEMSUSCHEM,2016,9(11):1255-1258. |
| APA | Xu, Zhanwei.,Yan, Peifang.,Liu, Kairui.,Wan, Lu.,Xu, Wenjuan.,...&Zhang, Z. Conrad.(2016).Synthesis of Bis(hydroxylmethylfurfuryl)amine Monomers from 5-Hydroxymethylfurfural.CHEMSUSCHEM,9(11),1255-1258. |
| MLA | Xu, Zhanwei,et al."Synthesis of Bis(hydroxylmethylfurfuryl)amine Monomers from 5-Hydroxymethylfurfural".CHEMSUSCHEM 9.11(2016):1255-1258. |
入库方式： OAI收割
来源：大连化学物理研究所
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