Elementary photocatalytic chemistry on TiO2 surfaces
文献类型：期刊论文
| 作者 | Guo, Qing2; Zhou, Chuanyao2; Ma, Zhibo2; Ren, Zefeng1,3,4; Fan, Hongjun2; Yang, Xueming2 |
| 刊名 | CHEMICAL SOCIETY REVIEWS
 |
| 出版日期 | 2016-07-07 |
| 卷号 | 45期号:13页码:3701-3730 |
| ISSN号 | 0306-0012 |
| DOI | 10.1039/c5cs00448a |
| 文献子类 | Review |
| 英文摘要 | Photocatalytic hydrogen production and pollutant degradation provided both great opportunities and challenges in the field of sustainable energy and environmental science. Over the past few decades, we have witnessed fast growing interest and efforts in developing new photocatalysts, improving catalytic efficiency and exploring the reaction mechanism at the atomic and molecular levels. Owing to its relatively high efficiency, nontoxicity, low cost and high stability, TiO2 becomes one of the most extensively investigated metal oxides in semiconductor photocatalysis. Fundamental studies on well characterized single crystals using ultrahigh vacuum based surface science techniques could provide key microscopic insight into the underlying mechanism of photocatalysis. In this review, we have summarized recent progress in the photocatalytic chemistry of hydrogen, water, oxygen, carbon monoxide, alcohols, aldehydes, ketones and carboxylic acids on TiO2 surfaces. We focused this review mainly on the rutile TiO2(110) surface, but some results on the rutile TiO2(011), anatase TiO2(101) and (001) surfaces are also discussed. These studies provided fundamental insights into surface photocatalysis as well as stimulated new investigations in this exciting field. At the end of this review, we have discussed how these studies can help us to develop new photocatalysis models. |
| WOS关键词 | RUTILE TIO2(110) SURFACE ; FINAL-STATE DISTRIBUTIONS ; SINGLE-CRYSTAL SURFACE ; METAL-OXIDE SURFACES ; SCANNING-TUNNELING-MICROSCOPY ; INTERFACIAL ELECTRON-TRANSFER ; 1ST PRINCIPLES CALCULATIONS ; FRACTAL REACTION-KINETICS ; BAND-GAP EXCITATION ; VISIBLE-LIGHT |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000378892400008 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170484]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Ren, Zefeng; Fan, Hongjun; Yang, Xueming |
| 作者单位 | 1.Peking Univ, Sch Phys, Beijing 100871, Peoples R China 2.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 3.Peking Univ, Int Ctr Quantum Mat, Beijing 100871, Peoples R China 4.Collaborat Innovat Ctr Quantum Matter, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Qing,Zhou, Chuanyao,Ma, Zhibo,et al. Elementary photocatalytic chemistry on TiO2 surfaces[J]. CHEMICAL SOCIETY REVIEWS,2016,45(13):3701-3730. |
| APA | Guo, Qing,Zhou, Chuanyao,Ma, Zhibo,Ren, Zefeng,Fan, Hongjun,&Yang, Xueming.(2016).Elementary photocatalytic chemistry on TiO2 surfaces.CHEMICAL SOCIETY REVIEWS,45(13),3701-3730. |
| MLA | Guo, Qing,et al."Elementary photocatalytic chemistry on TiO2 surfaces".CHEMICAL SOCIETY REVIEWS 45.13(2016):3701-3730. |
入库方式： OAI收割
来源：大连化学物理研究所
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