Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones
文献类型：期刊论文
| 作者 | Liu, Cheng-Hang; Zhuang, Zhe; Bose, Sritama; Yu, Zhi-Xiang |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2016-06-02 |
| 卷号 | 72期号:22页码:2752-2755 |
| 关键词 | Fe-2(Co)(9) 5+1 Cycloaddition Vinylcyclopropane Co |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2016.01.046 |
| 文献子类 | Article |
| 英文摘要 | A Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes (VCPs) and CO to alpha, beta-cyclohexenones has been developed. The reaction can tolerate aryl and aliphatic groups at the alpha-position of VCPs, while VCP substrates with vinyl or alkynyl substitutions are not suitable ones. In addition, this reaction can also be used to synthesize bicyclic rings if an aryl group is attached to the vinyl moiety of the substrate. Compared to the Fe(CO)(5)-mediated [5+1] reaction, the use of cheap and safe Fe-2(CO)(9) and abandoning the photo-irradiation conditions are the two major advantages of the present method. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS关键词 | IRON CARBONYL-COMPLEXES ; DIELS-ALDER REACTION ; TRANSITION-METAL ; ORGANIC-SYNTHESIS ; ALKENYL CYCLOPROPANES ; DIIRON NONACARBONYL ; BOND ACTIVATION ; MONOXIDE ; PENTACARBONYL ; CATALYSIS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000376703700008 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170588]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhi-Xiang |
| 作者单位 | Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Cheng-Hang,Zhuang, Zhe,Bose, Sritama,et al. Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones[J]. TETRAHEDRON,2016,72(22):2752-2755. |
| APA | Liu, Cheng-Hang,Zhuang, Zhe,Bose, Sritama,&Yu, Zhi-Xiang.(2016).Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones.TETRAHEDRON,72(22),2752-2755. |
| MLA | Liu, Cheng-Hang,et al."Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones".TETRAHEDRON 72.22(2016):2752-2755. |
入库方式： OAI收割
来源：大连化学物理研究所
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