Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening
文献类型：期刊论文
| 作者 | Zhou, Xukai; Yu, Songjie; Qi, Zisong; Kong, Lingheng; Li, Xingwei |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2016-06-03 |
| 卷号 | 81期号:11页码:4869-4875 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.6b00650 |
| 文献子类 | Article |
| 英文摘要 | The rhodium(III)-catalyzed regioselective alkylation of (hetero)arenes using cyclopropanols as a reactive and efficient coupling, partner under oxidative conditions has been developed. This coupling occurred at room temperature via C-H activation of arenes and C-C cleavage of cyclopropanols. Various types of (hetero)arenes (indolines, carbazole, tetrahydrocarbazole, pyrrole, thiophene, etc.) were all successfully reacted under the present conditions. This protocol provides the facile and efficient construction of C7-alkylated indoline scaffolds. |
| WOS关键词 | PALLADIUM-CATALYZED REACTIONS ; BOND FORMATION ; CONJUGATE ADDITION ; ALLYLIC ALKYLATION ; C(SP(3))-H BONDS ; INDOLE ALKALOIDS ; ARYL BROMIDES ; ARENES ; FUNCTIONALIZATION ; ARYLATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000377319500048 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170610]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xukai,Yu, Songjie,Qi, Zisong,et al. Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(11):4869-4875. |
| APA | Zhou, Xukai,Yu, Songjie,Qi, Zisong,Kong, Lingheng,&Li, Xingwei.(2016).Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening.JOURNAL OF ORGANIC CHEMISTRY,81(11),4869-4875. |
| MLA | Zhou, Xukai,et al."Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C-H Activation and Ring Opening".JOURNAL OF ORGANIC CHEMISTRY 81.11(2016):4869-4875. |
入库方式： OAI收割
来源：大连化学物理研究所
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