Pd@C3N4 Nanocatalyst for Highly Efficient Hydrogen Storage System Based on Potassium Bicarbonate/Formate
文献类型：期刊论文
| 作者 | Shao, Xianzhao1,2; Xu, Jinming1; Huang, Yanqiang1; Su, Xiong1; Duan, Hongmin1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2016-07-01 |
| 卷号 | 62期号:7页码:2410-2418 |
| 关键词 | Bicarbonate Carbon Nitride Formate Hydrogenation Palladium |
| ISSN号 | 0001-1541 |
| DOI | 10.1002/aic.15218 |
| 文献子类 | Article |
| 英文摘要 | Formate/bicarbonate system has several desirable properties such as noncorrosive and nonirritating nature, as well as facile handling, which make it an attractive candidate for a safe, reversible hydrogen storage material. Herein, Pd nanoparticles supported on mesoporous graphitic carbon nitride (mpg-C3N4) for formate-based reversible hydrogen storage is reported. The as-developed Pd/mpg-C3N4 material was shown to be a superior catalyst for the hydrogenation of high concentrations of bicarbonate to formate under mild conditions. The effects of reaction temperature, H-2 pressure, and bicarbonate concentration on the hydrogenation of bicarbonate to formate were investigated. The catalytic performance remained steady with high activity up to six hydrogenation cycles. The interaction between mpg-C3N4 and Pd nanoparticles and the concerted effects of the nitrogen species located at mpg-C3N4 and bicarbonate played a synergetic role in the enhancement of the performance of the catalyst for hydrogenation. (c) 2016 American Institute of Chemical Engineers |
| WOS关键词 | CARBON-DIOXIDE ACTIVATION ; FORMIC-ACID ; AQUEOUS-SOLUTION ; HOMOGENEOUS HYDROGENATION ; AMBIENT CONDITIONS ; CATALYTIC-ACTIVITY ; MILD CONDITIONS ; FORMATE SALTS ; PD ; CO2 |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000377274600012 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170616]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Huang, Yanqiang; Wang, Xiaodong |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Shaanxi Univ Technol, Sch Chem & Environm Sci, Shaanxi Prov Key Lab Catalyt Fdn & Applicat, Hanzhong 723001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, Xianzhao,Xu, Jinming,Huang, Yanqiang,et al. Pd@C3N4 Nanocatalyst for Highly Efficient Hydrogen Storage System Based on Potassium Bicarbonate/Formate[J]. AICHE JOURNAL,2016,62(7):2410-2418. |
| APA | Shao, Xianzhao.,Xu, Jinming.,Huang, Yanqiang.,Su, Xiong.,Duan, Hongmin.,...&Zhang, Tao.(2016).Pd@C3N4 Nanocatalyst for Highly Efficient Hydrogen Storage System Based on Potassium Bicarbonate/Formate.AICHE JOURNAL,62(7),2410-2418. |
| MLA | Shao, Xianzhao,et al."Pd@C3N4 Nanocatalyst for Highly Efficient Hydrogen Storage System Based on Potassium Bicarbonate/Formate".AICHE JOURNAL 62.7(2016):2410-2418. |
入库方式： OAI收割
来源：大连化学物理研究所
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