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Chiral Ferrocenyl P,N-Ligands for Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Propargylic Esters with beta-Ketoesters: Access to Functionalized Chiral 2,3-Dihydrofurans

文献类型：期刊论文

作者Zhou, Yong1,3; Zhu, Fu-Lin2; Liu, Zhen-Ting2; Zhou, Xiao-Mao1,3; Hu, Xiang-Ping2
刊名ORGANIC LETTERS
出版日期2016-06-03
卷号18期号:11页码:2734-2737
ISSN号1523-7060
DOI10.1021/acs.orglett.6b01192
文献子类Article
英文摘要A highly enantioselective palladium-catalyzed [3 + 2] cycloaddition of propargylic esters with, beta-ketoesters has been realized by employing a newly developed chiral ferrocene/benzimidazole-based P,N-ligand. This protocol features a good tolerance of functional groups in both propargylic esters and beta-ketoesters, thereby delivering a variety of highly functionalized chiral 2,3-dihydrofurans bearing an exocyclic double bond at the 3-position in good yields and with high enantioselectivities (up to 98% ee).
WOS关键词ONE-POT SYNTHESIS ; HIGHLY ENANTIOSELECTIVE SYNTHESIS ; FULLY SUBSTITUTED PYRROLES ; FEIST-BENARY REACTION ; 1,3-DICARBONYL COMPOUNDS ; ORGANIC-SYNTHESIS ; TANDEM REACTION ; PRIMARY AMINES ; KETO-ESTERS ; DIHYDROFURANS
WOS研究方向Chemistry
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000377319000055
源URL[http://cas-ir.dicp.ac.cn/handle/321008/170622]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Zhou, Xiao-Mao; Hu, Xiang-Ping
作者单位1.Hunan Acad Agr Sci, Biotechnol Res Ctr, Changsha 410125, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Collaborat Innovat Ctr Field Weeds Control, Loudi 417000, Hunan, Peoples R China
推荐引用方式
GB/T 7714		 Zhou, Yong,Zhu, Fu-Lin,Liu, Zhen-Ting,et al. Chiral Ferrocenyl P,N-Ligands for Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Propargylic Esters with beta-Ketoesters: Access to Functionalized Chiral 2,3-Dihydrofurans[J]. ORGANIC LETTERS,2016,18(11):2734-2737.
APA Zhou, Yong,Zhu, Fu-Lin,Liu, Zhen-Ting,Zhou, Xiao-Mao,&Hu, Xiang-Ping.(2016).Chiral Ferrocenyl P,N-Ligands for Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Propargylic Esters with beta-Ketoesters: Access to Functionalized Chiral 2,3-Dihydrofurans.ORGANIC LETTERS,18(11),2734-2737.
MLA Zhou, Yong,et al."Chiral Ferrocenyl P,N-Ligands for Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Propargylic Esters with beta-Ketoesters: Access to Functionalized Chiral 2,3-Dihydrofurans".ORGANIC LETTERS 18.11(2016):2734-2737.

入库方式： OAI收割

来源：大连化学物理研究所

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