Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3
文献类型：期刊论文
| 作者 | Yang, Yanliang1,2; Ma, Jiping1; Jia, Xiuquan1,3; Du, Zhongtian1; Duan, Ying2; Xu, Jie1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:56页码:51221-51228 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra05680f |
| 文献子类 | Article |
| 英文摘要 | Al2O3 modified by alkaline earth metals M-Al2O3 (M - Mg, Ca, Sr, Ba) was synthesised by coprecipitation method. The nickel-based catalysts supported by M-Al2O3 were prepared by impregnation method. The catalysts were characterized by TEM, N-2 adsorption/desorption, XRD, H-2-TPR, NH3-TPD and XPS, and used for the direct hydrogenation of furfural to tetrahydrofurfuryl alcohol (THFA) in water. The reaction was demonstrated to proceed through furfuryl alcohol as an intermediate. The modification of Al2O3 by alkaline earth metals has a significant effect on the activity and selectivity of THFA. A high yield of THFA was obtained over Ni/Ba-Al2O3 under optimized conditions. Moreover, the catalyst is recyclable and reusable at least four times without significant loss of the conversion of furfural and selectivity of THFA. |
| WOS关键词 | CATALYTIC-HYDROGENATION ; ALLOY CATALYST ; CONVERSION ; BIOMASS ; CHEMICALS ; TRANSFORMATION ; HYDROGENOLYSIS ; CYCLOPENTANONE ; REDUCTION ; PLATFORM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000377515200093 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170628]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xu, Jie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Yanliang,Ma, Jiping,Jia, Xiuquan,et al. Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3[J]. RSC ADVANCES,2016,6(56):51221-51228. |
| APA | Yang, Yanliang,Ma, Jiping,Jia, Xiuquan,Du, Zhongtian,Duan, Ying,&Xu, Jie.(2016).Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3.RSC ADVANCES,6(56),51221-51228. |
| MLA | Yang, Yanliang,et al."Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3".RSC ADVANCES 6.56(2016):51221-51228. |
入库方式： OAI收割
来源：大连化学物理研究所
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