Stability of SrO-La2O3-Al2O3-SiO2 glass sealants in high-temperature air and steam
文献类型:期刊论文
作者 | Wang, Xiuling1,2; Ou, Ding Rong1; Zhao, Zhe1; Cheng, Mojie1 |
刊名 | CERAMICS INTERNATIONAL
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出版日期 | 2016-05-01 |
卷号 | 42期号:6页码:7514-7523 |
关键词 | Solid Oxide Fuel Cells/Solid Oxide Electrolysis Cells Glass Sealants Network Structure Glass Stability |
ISSN号 | 0272-8842 |
DOI | 10.1016/j.ceramint.2016.01.158 |
文献子类 | Article |
英文摘要 | SrO-La2O3-Al2O3-SiO2 glasses with different SrO content are prepared and their stability in high temperature air and steam are investigated. All glasses are stable during 1000 h test at 800 degrees C in air. Nevertheless, the high SrO glasses (>= 40 mol%) are devitrified on the surfaces when they are treated at 850-900 degrees C in air or exposed to steam. Si-29 magic angle spinning nuclear magnetic resonance study reveals weaker connections between [SiO4] tetrahedral units and increased micro heterogeneity of glass networks with increasing SrO content, which should be responsible to the lower stability of the high SrO glasses. It indicates that a careful control of SrO content is necessary to develop stable SrO La2O3-Al2O3-SiO2 glass sealants for solid oxide fuel cells and solid oxide electrolysis cells. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved. |
WOS关键词 | OXIDE FUEL-CELLS ; STRUCTURE-PROPERTY RELATIONSHIPS ; SI-29 MAS-NMR ; CERAMIC SEALANTS ; SILICATE-GLASSES ; PHYSICAL-PROPERTIES ; CRYSTALLIZATION KINETICS ; MECHANICAL STABILITY ; THERMAL-STABILITY ; NETWORK STRUCTURE |
WOS研究方向 | Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000372676000118 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170664] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Cheng, Mojie |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cells, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Xiuling,Ou, Ding Rong,Zhao, Zhe,et al. Stability of SrO-La2O3-Al2O3-SiO2 glass sealants in high-temperature air and steam[J]. CERAMICS INTERNATIONAL,2016,42(6):7514-7523. |
APA | Wang, Xiuling,Ou, Ding Rong,Zhao, Zhe,&Cheng, Mojie.(2016).Stability of SrO-La2O3-Al2O3-SiO2 glass sealants in high-temperature air and steam.CERAMICS INTERNATIONAL,42(6),7514-7523. |
MLA | Wang, Xiuling,et al."Stability of SrO-La2O3-Al2O3-SiO2 glass sealants in high-temperature air and steam".CERAMICS INTERNATIONAL 42.6(2016):7514-7523. |
入库方式: OAI收割
来源:大连化学物理研究所
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