Template-assisted synthesis of hierarchically porous Co3O4 with enhanced oxygen evolution activity
文献类型:期刊论文
作者 | Yao, Lan1,2; Zhong, Hexiang1; Deng, Chengwei1,2; Li, Xianfeng1,3; Zhang, Huamin1,3 |
刊名 | JOURNAL OF ENERGY CHEMISTRY
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出版日期 | 2016 |
卷号 | 25期号:1页码:153-157 |
关键词 | Oxygen Evolution Reaction Co3o4 Non-precious Metal Catalysts High Activity High Stability |
ISSN号 | 2095-4956 |
DOI | 10.1016/j.jechem.2015.11.013 |
文献子类 | Article |
英文摘要 | Oxygen evolution reaction (OER) is one of the most important reactions in the energy storage devices such as metal air batteries and unitized regenerative fuel cells (URFCs). However, the kinetically sluggishness of OER and the high prices as well as the scarcity of the most active precious metal electrocatalysts are the major bottleneck in these devices. Developing low-cost non-precious metal catalysts with high activity and stability for OER is highly desirable. A facile, in situ template method combining the dodecyl benzene sulfuric acid sodium (SDBS) assisted hydrothermal process with subsequent high-temperature treatment was developed to prepare porous Co3O4 with improved surface area and hierarchical porous structure as precious catalysts alternative for oxygen evolution reaction (OER). Due to the unique structure, the as-prepared catalyst shows higher electrocatalytic activity than Co3O4 prepared by traditional thermal-decomposition method (noted as Co3O4-T) and commercial IrO2 catalyst for OER in 0.1 M KOH aqueous solution. Moreover, it displays improved stability than Co3O4-T. The results demonstrate a highly efficient, scalable, and low cost method for developing highly active and stable OER electrocatalysts in alkaline solutions. (C) 2015 Science Press and Dalian Institute of Chemical Physics. All rights reserved. |
WOS关键词 | LITHIUM-ION BATTERIES ; DEPENDENT SELF-ORGANIZATION ; NONPRECIOUS METAL CATALYST ; MESOPOROUS COBALT OXIDE ; AIR BATTERIES ; FACILE SYNTHESIS ; WATER ; MICROSPHERES ; ELECTRODES ; NANOWIRES |
WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000373244400021 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170672] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Zhong, Hexiang; Zhang, Huamin |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Div Energy Storage, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Yao, Lan,Zhong, Hexiang,Deng, Chengwei,et al. Template-assisted synthesis of hierarchically porous Co3O4 with enhanced oxygen evolution activity[J]. JOURNAL OF ENERGY CHEMISTRY,2016,25(1):153-157. |
APA | Yao, Lan,Zhong, Hexiang,Deng, Chengwei,Li, Xianfeng,&Zhang, Huamin.(2016).Template-assisted synthesis of hierarchically porous Co3O4 with enhanced oxygen evolution activity.JOURNAL OF ENERGY CHEMISTRY,25(1),153-157. |
MLA | Yao, Lan,et al."Template-assisted synthesis of hierarchically porous Co3O4 with enhanced oxygen evolution activity".JOURNAL OF ENERGY CHEMISTRY 25.1(2016):153-157. |
入库方式: OAI收割
来源:大连化学物理研究所
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