Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters
文献类型：期刊论文
| 作者 | Li, Yunyun; Wang, Fen; Yu, Songjie; Li, Xingwei |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2016-03-17 |
| 卷号 | 358期号:6页码:880-886 |
| 关键词 | Carbocyclization C-h Activation Alpha-diazo Esters Iridium(Iii) And Rhodium(Iii) Catalysis 2-phenylimidazo[1 2-a]Pyridines |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201500709 |
| 文献子类 | Article |
| 英文摘要 | Iridium(III) and rhodium(III) complexes can catalyze the carbocyclization between 2-phenylimidazo[1,2-a]pyridine and alpha-diazo esters. The reaction occurs via C-H activation and dialkylation of the arene followed by intramolecular nucleophilic substitution. Iridium(III) and rhodium(III) catalysis offer complementary scopes with respect to the alpha-diazo esters. |
| WOS关键词 | C-H BOND ; RH(III)-CATALYZED OXIDATIVE ANNULATION ; CARBENE MIGRATORY INSERTION ; N BOND ; CHELATION-ASSISTANCE ; INTERNAL ALKYNES ; NATURAL-PRODUCTS ; DIRECT ARYLATION ; DIRECTING GROUP ; ACTIVATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000373159200005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170682]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yunyun,Wang, Fen,Yu, Songjie,et al. Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(6):880-886. |
| APA | Li, Yunyun,Wang, Fen,Yu, Songjie,&Li, Xingwei.(2016).Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters.ADVANCED SYNTHESIS & CATALYSIS,358(6),880-886. |
| MLA | Li, Yunyun,et al."Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters".ADVANCED SYNTHESIS & CATALYSIS 358.6(2016):880-886. |
入库方式： OAI收割
来源：大连化学物理研究所
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