Designing highly efficient Rh/CPOL-bp&PPh3 heterogenous catalysts for hydroformylation of internal and terminal olefins
文献类型：期刊论文
| 作者 | Li, Cunyao1,3; Xiong, Kai4; Yan, Li2; Jiang, Miao1,3; Song, Xiangen1; Wang, Tao1,3; Chen, Xingkun1,3; Zhan, Zhuangping4; Ding, Yunjie1,2 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:7页码:2143-2149 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c5cy01655j |
| 文献子类 | Article |
| 英文摘要 | Vinyl functionalized Biphephos ligand, denoted as vinyl biphephos, has been succesfully synthesized. Copolymerization of vinyl biphephos with tris(4-vinphenyl) phosphane can afford an efficient Porous Organic Polymer (POP), CPOL-bp&PPh3. The ultimately formed Rh/CPOL-bp&PPh3 heterogeneous catalyst showed excellent performance in converting terminal olefins to the corresponding linear aldehydes with high regioselectivity (l/b = 96:4-98:2), activity and stability, even better than the comparable homogeneous Rh + vinyl biphephos system. Notably, isomerizing hydrofromylation of internal olefins (2-heptene, 2-octene, trans-3-hexene) was also performed with high regioselectivity (l/b = 92 :8-93: 7) using the Rh/CPOL-bp&PPh3 heterogeneous catalyst. |
| WOS关键词 | COVALENT ORGANIC FRAMEWORKS ; RHODIUM-BIPHEPHOS-CATALYST ; TETRAPHOSPHORUS LIGANDS ; REGIOSELECTIVE HYDROAMINOMETHYLATION ; ISOMERIZATION-HYDROFORMYLATION ; SELECTIVE HYDROFORMYLATION ; BIPHASIC HYDROFORMYLATION ; CARBON NANOTUBES ; HYDROGEN STORAGE ; HIGHER ALKENES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000373608400015 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170714]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yan, Li; Ding, Yunjie |
| 作者单位 | 1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 4.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Cunyao,Xiong, Kai,Yan, Li,et al. Designing highly efficient Rh/CPOL-bp&PPh3 heterogenous catalysts for hydroformylation of internal and terminal olefins[J]. CATALYSIS SCIENCE & TECHNOLOGY,2016,6(7):2143-2149. |
| APA | Li, Cunyao.,Xiong, Kai.,Yan, Li.,Jiang, Miao.,Song, Xiangen.,...&Ding, Yunjie.(2016).Designing highly efficient Rh/CPOL-bp&PPh3 heterogenous catalysts for hydroformylation of internal and terminal olefins.CATALYSIS SCIENCE & TECHNOLOGY,6(7),2143-2149. |
| MLA | Li, Cunyao,et al."Designing highly efficient Rh/CPOL-bp&PPh3 heterogenous catalysts for hydroformylation of internal and terminal olefins".CATALYSIS SCIENCE & TECHNOLOGY 6.7(2016):2143-2149. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。