Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids
文献类型：期刊论文
| 作者 | Wu, Guojiao1; Deng, Yifan1; Luo, Haiqing1; Zhou, Junliang1; Li, Tianjiao1; Zhang, Yan1; Wang, Jianbo1,2 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:30页码:5266-5268 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c6cc01750a |
| 文献子类 | Article |
| 英文摘要 | alpha-Halo-N-tosylhydrazones are employed as reagents for the formation of multiple carbon-carbon bonds in the three-component reactions. In this transformation, a strategy has been designed to generate the diazo intermediate by using a nucleophile to react with the azoalkene intermediate generated in situ from the alpha-halo-N-tosylhydrazone. The diazo intermediate thus generated further undergoes transition-metal-free C-C bond forming reaction with arylboronic acids. |
| WOS关键词 | SITU GENERATED 1,2-DIAZA-1,3-DIENES ; IN-SITU ; EFFICIENT SYNTHESIS ; CARBONYL-COMPOUNDS ; COUPLING REACTIONS ; BORONIC ACIDS ; AZOALKENES ; CARBENE ; CYCLOADDITION ; INSERTION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000373687400011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170720]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Minist Educ,BNLMS, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Guojiao,Deng, Yifan,Luo, Haiqing,et al. Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids[J]. CHEMICAL COMMUNICATIONS,2016,52(30):5266-5268. |
| APA | Wu, Guojiao.,Deng, Yifan.,Luo, Haiqing.,Zhou, Junliang.,Li, Tianjiao.,...&Wang, Jianbo.(2016).Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids.CHEMICAL COMMUNICATIONS,52(30),5266-5268. |
| MLA | Wu, Guojiao,et al."Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids".CHEMICAL COMMUNICATIONS 52.30(2016):5266-5268. |
入库方式： OAI收割
来源：大连化学物理研究所
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