Evolution of iron species for promoting the catalytic performance of FeZSM-5 in phenol oxidation
文献类型：期刊论文
| 作者 | Luo, Lei1; Dai, Chengyi1; Zhang, Anfeng1; Wang, Junhu2; Song, Chunshan1,3,4; Guo, Xinwen1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:39页码:32789-32797 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra03552c |
| 文献子类 | Article |
| 英文摘要 | Facile modification of FeZSM-5 utilizing an organic directing agent (ODA) for iron species evolution toward better Fenton activity was developed. Pristine FeZSM-5, prepared hydrothermally using tetrapropylammonium bromide as the ODA, was thermally treated in nitrogen or air atmosphere for comparison. The as-prepared FeZSM-5 were evaluated by XRD, SEM, TGA, Ar physical adsorption, H2-TPR, UV-Vis, XPS and Mossbauer spectra, which confirmed well-dispersed iron species and partial transformation of framework iron to non-framework iron and Fe(III) to Fe(II) during thermal treatment in N-2. The phenol oxidation reaction was applied as a probe reaction and phenol conversion can be improved from 44% to 90% within 60 minutes. By thermal treatment in N-2 atmosphere, the ODA plays an important role in modifying non-framework iron species from Fe(III) to Fe(II) ions which is desirable for improving catalytic activity in Fenton-like systems. The strategy utilizing the thermal reduction effect of the ODA on iron species is a reliable method for preparing well-dispersed and valence tunable iron oxide nanoparticles encapsulated in ZSM-5. |
| WOS关键词 | MAGNETIC NANOPARTICLES ; ORGANIC POLLUTANTS ; FENTON OXIDATION ; AQUEOUS-SOLUTION ; DEGRADATION ; ZEOLITES ; CARBON ; SILICALITE-1 ; SPECTROSCOPY ; MOSSBAUER |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000374045900045 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170728]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Song, Chunshan |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 3.Penn State Univ, EMS Energy Inst, PSU DUT Joint Ctr Energy Res, University Pk, PA 16802 USA 4.Penn State Univ, Dept Energy & Mineral Engn, University Pk, PA 16802 USA |
| 推荐引用方式 GB/T 7714 | Luo, Lei,Dai, Chengyi,Zhang, Anfeng,et al. Evolution of iron species for promoting the catalytic performance of FeZSM-5 in phenol oxidation[J]. RSC ADVANCES,2016,6(39):32789-32797. |
| APA | Luo, Lei,Dai, Chengyi,Zhang, Anfeng,Wang, Junhu,Song, Chunshan,&Guo, Xinwen.(2016).Evolution of iron species for promoting the catalytic performance of FeZSM-5 in phenol oxidation.RSC ADVANCES,6(39),32789-32797. |
| MLA | Luo, Lei,et al."Evolution of iron species for promoting the catalytic performance of FeZSM-5 in phenol oxidation".RSC ADVANCES 6.39(2016):32789-32797. |
入库方式： OAI收割
来源：大连化学物理研究所
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