Nitrogen ligands in two-dimensional covalent organic frameworks for metal catalysis
文献类型：期刊论文
| 作者 | Xu, Feifei2; Zhang, Jianqiang1; Peng, Yongsheng2; Leng, Wenguang2; Gao, Yanan2; Chai, Jinling1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016-04-01 |
| 卷号 | 37期号:4页码:468-475 |
| 关键词 | Covalent Organic Framework Metal Catalysis Heck Reaction Nitrogen Ligand Palladium |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(15)61050-6 |
| 文献子类 | Article |
| 英文摘要 | We introduced bipyridine ligands into a series of two-dimensional (2D) covalent organic frameworks (COFs) using 2,2'-bipyridine-5,5'-dicarbaldehyde (2,2'-BPyDCA) as a component in the mixed building blocks. The framework of the COFs was formed by the linkage of imine groups. The ligand content in the COFs was synthetically tuned by the content of 2,2'-BPyDCA, and thus the amount of metal, palladium(II) acetate, bonded to the nitrogen ligands could be manipulated. Both the bipyridine ligands and imine groups can coordinate with Pd(II) ions, but the loading position can be varied, with one ligand favoring binding in the space between adjacent COFs' layers and the other ligand favoring binding within the pores of the COFs. The Pd(II)-loaded COFs exhibited good catalytic activity for the Heck reaction. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | CRYSTALLINE ; STORAGE ; HYDROGEN ; CONSTRUCTION ; STABILITY ; FILMS |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000374082700002 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170746]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Leng, Wenguang; Chai, Jinling |
| 作者单位 | 1.Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Feifei,Zhang, Jianqiang,Peng, Yongsheng,et al. Nitrogen ligands in two-dimensional covalent organic frameworks for metal catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(4):468-475. |
| APA | Xu, Feifei,Zhang, Jianqiang,Peng, Yongsheng,Leng, Wenguang,Gao, Yanan,&Chai, Jinling.(2016).Nitrogen ligands in two-dimensional covalent organic frameworks for metal catalysis.CHINESE JOURNAL OF CATALYSIS,37(4),468-475. |
| MLA | Xu, Feifei,et al."Nitrogen ligands in two-dimensional covalent organic frameworks for metal catalysis".CHINESE JOURNAL OF CATALYSIS 37.4(2016):468-475. |
入库方式： OAI收割
来源：大连化学物理研究所
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